Vol. 24 Núm. 4 (2025): Revista UIS Ingenierías
Artículos

Obtención de silicatos alcalinos a partir de un residuo agroindustrial

Ruby Mejía-de Gutiérrez
Universidad del Valle
Mónica Villaquirán-Caicedo
Universidad del Valle
Marisol Gordillo-Suárez
Universidad Autónoma de Occidente

Publicado 2025-11-26

Palabras clave

  • cascarilla de arroz,
  • ceniza de cascarilla de arroz,
  • silicatos alcalinos,
  • silice precipitada,
  • geopolimero

Cómo citar

Mejía-de Gutiérrez, R., Villaquirán-Caicedo, M., & Gordillo-Suárez , M. (2025). Obtención de silicatos alcalinos a partir de un residuo agroindustrial. Revista UIS Ingenierías, 24(4), 65–80. https://doi.org/10.18273/revuin.v24n4-2025005

Resumen

Cascarilla de arroz (CA), proveniente de una arrocera de la región del Valle del Cauca, fue empleada en la síntesis de silicatos alcalinos, los cuales fueron validades en la producción de sílice precipitada y geopolímeros. La Ceniza de cascarilla de arroz (CCA) fue obtenida a partir de tratamientos químicos (TQ) y térmicos (TT) de la CA, y caracterizada por medio de técnicas como microscopia electrónica, análisis termogravimétrico y difracción de rayos X para conocer su calidad. Los resultados mostraron que la CCA-TQ (densidad de 2,03 g/cm3) presenta mayor contenido de sílice amorfa y mayor área específica en comparación de CCA-TT (densidad de 2,13 g/cm3), sin embargo, en ambos casos contienen más de 94% de SiO2 en su composición. La aplicación de optimización de variables de síntesis hidrotermal (relaciones molares NaOH/SiO2, H2O/SiO2, Temperatura, y Tiempo) a las CCA produjo silicatos alcalinos con alto contenido de SiO2 y baja alcalinidad, los cuales son aptos para la generación de sílice precipitada con 98% de pureza y geopolímeros que pueden alcanzar resistencias a compresión de hasta 37.9 MPa, siendo un 45,8% superior a geopolímeros producidos con un silicato comercial nacional.

Descargas

Los datos de descargas todavía no están disponibles.

Citas

  1. [1] L. A. September, N. Kheswa, N. S. Seroka, L. Khotseng, "Green synthesis of silica and silicon from agriculture residue sugarcane bagasse ash – a mini review", RSC Adv., vol. 13, no. 2, pp. 1370-1380, January 2023, doi: https://doi.org/10.1039/d2ra07490g.
  2. [2] T. Liou, Y. Tseng, T. Zhang, Z. Liu and J. Chen, "Rice husk char as a sustainable material for the preparation of graphene oxide-supported biocarbons with mesoporous structure: A characterization and adsorption study", Fuel, vol. 344, pp. 128042, July 2023, doi: https://doi.org/10.1016/j.fuel.2023.128042.
  3. [3] SK. S. Hossain, L. Mathur and P. K. Roy, "Rice husk/rice husk ash as an alternative source of silica in ceramics: A review", J. Asian Ceram. Soc., vol. 6, pp. 299-313, October 2018, doi: https://doi.org/10.1080/21870764.2018.1539210.
  4. [4] I. Hamidu, B. Afotey, B. Kwakye-Awuah and D. Adjah Anang, "Synthesis of silica and silicon from rice husk feedstock: A review", Heliyon, vol. 11, no. 4, pp. e42491, February 2025, doi: https://doi.org/10.1016/j.heliyon.2025.e42491.
  5. [5] E. Folleto, G. Ederson, H. Oliverira and S. Jahn, “Conversion of Rice Hull Ash into soluble sodium silicate", Mater. Res., vol. 9, no. 3, pp. 335-338, 2006, doi: https://doi.org/10.1590/S1516-14392006000300014.
  6. [6] U. Kalapathy, A. Proctor and J. Shultz, "An improved method for production silica from rice hull ash", Bioresource Tech., vol. 85, no. 3, pp. 285-289, December 2002, doi: https://doi.org/10.1016/S0960-8524(02)00116-5.
  7. [7] H. Mukunda, S. Dasappa, P. Paul, N. Rajan and D. Subbukrishna, "A Novel Process and Apparatus for the Manufacture of Precipitated Silica from Rice Husk Ash". India Patente Wo 2004/073600, 2004.
  8. [8] B. Triviño, I. Gomez, "Obtención y caracterización de carburo y nitruro de silicio a partir de cascarilla de arroz", Ciencias UANL, vol. VI, no. 19, pp. 21-27, Abril-Junio 2003.
  9. [9] J. Goncalvez, G. Da Silva, L. Lima, D. Morgado, M. Nalin, L. Armas, V. C. and J. Menezes, "Production of Transparent Soda-Lime Glass from Rice Husk Containing Iron and Manganese Impurities", Ceramics, vol. 3, no. 4, pp. 494-506, October 2020, doi: https://doi.org/10.3390/ceramics3040040.
  10. [10] C. C. Yang, T.H. Liou, "Synthesis and surface characteristics of nanosilica produced from alkali-extracted rice husk ash", Mater. Sci. Eng B, vol. 176, no. 7, pp. 521-529, April 2011, doi: http://dx.doi.org/10.1016/j.mseb.2011.01.007.
  11. [11] M. Villaquiran-Caicedo and R. Mejia de Gutierrez, "Mechanical and microstructural analysis of geopolymer composites based on metakaolin and recycled silica", J. Am. Ceram. Soc., vol. 102, no. 6, pp. 3653-3662, November 2018, doi: https://doi.org/10.1111/jace.16208.
  12. [12] J. Mejia, R. Mejia de Gutierrez, F. Puertas, "Rice husk ash as a source of silica in alkali-activated fly ash and granulated blast furnace slag systems", Mater. Const., vol. 63, no. 311, pp. 361-375, September 2013, doi: https://doi.org/10.3989/mc.2013.04712.
  13. [13] B. Nanda, J. Mishra and S. Patro, "Synthesis of rice husk ash based alkaline activators for geopolymer binder systems: A review", J. Build. Eng., vol. 91, pp. 109694, August 2024, doi: https://doi.org/10.1016/j.jobe.2024.109694.
  14. [14] D. Das, A. Golabiewska and P. Rout, "Geopolymer bricks: The next generation of construction materials for sustainable environment. Review", Constr. Build. Mater., vol. 445, pp. 137876, September 2024, doi: https://doi.org/10.1016/j.conbuildmat.2024.137876.
  15. [15] Y. Deng, Z. Sha, X. Wang, K. Duan, W. Xue, I. Beadham, X. Xiao and C. Zhang, “Exploration of Key Factors in the Preparation of Highly Hydrophobic Silica Aerogel from Rice Husk Ash Assisted by Machine Learning", Gels, vol. 11, no. 1, pp. 74, January 2025, doi: https://doi.org/10.3390/gels11010074.
  16. [16] N. Asim, M. Badiei, M. Alghoul, M. Mohammad, A. Fudholi, M. Akhtaruzzaman, N. Amin and K. Sopian, “Biomass and Industrial Wastes as Resource Materials for Aerogel Preparation: Opportunities, Challenges, and Research Directions", Ind. Eng. Chem. Res., vol. 58, pp. 17621-17645, August 2019, doi: https://doi.org/10.1021/acs.iecr.9b02661.
  17. [17] S. Cui, S.-W. Yu, B.-L. Lin, X.-D.-. Shen and D. Gu, “Preparation of SiO2 Aerogel from Rice Husk Ash", RSC Adv., vol. 5, no. 81, pp. 65818-65826, July 2015, doi: https://doi.org/10.1039/C5RA08886K.
  18. [18] N.F. Mohamad et al., “Synthesis and Characterization of Silica Aerogel from Rice Husk with Ambient Pressure Drying Method", J. Phys.: Conf. Ser., vol. 1535, pp. 012049, 2020, doi: https://doi.org/10.1088/1742-6596/1535/1/012049.
  19. [19] P. Metha, “Siliceous Ashes and Hydraulic Cements Prepared Therefrom». Belgian Patente 802909, 1973.
  20. [20] K. Mensaray and A. Ghaly, “Thermal degradation of rice husks in nitrogen atmosphere", Bioresour. Technol., vol. 65, pp. 13-20, July-August 1998, doi: https://doi.org/10.1016/S0960-8524(98)00031-5.
  21. [21] R. Chouhan, B. Kujur, S. Amritphale and N. Chandra, “Effect of temperature of ashing of rice husk on the compressive strength of lime-rice husk silica mortar", Silicates Industriels, vol. 65, pp. 67-71, 2000.
  22. [22] M. Islam, M. Hossen, K. E-Zahan, M. Asraf, C. Zakaria, Hayatullah and S. Rana, “Effect of temperature and time on purity, morphology and phase transformations of silica from rice husk", Chem. Inorg. Mater., vol. 5, pp. 100092, April 2025. https://doi.org/10.1016/j.cinorg.2025.100092.
  23. [23] M. J. Antal, “Biomass pyrolysis: a review of the literature. Part I –Carbohydrate pyrolysis", In: Böer, K.W., Duffie, J.A. (eds) Advances Solar Energy, Springer, Boston, MA, 1983, pp. 61-111, doi: https://doi.org/10.1007/978-1-4684-8992-7_3.
  24. [24] M. Patel, A. Karera and P. Prasanna, “Effect of thermal and chemical tretaments on carbon and silica contents in rice husk", J. Mater. Sci, vol. 22, pp. 2457-2464, July 1987. https://doi.org/10.1007/bf01082130.
  25. [25] Q. Feng, S. Sugita, M. Shoya, H. Yamamichi and Y. Isojima, “Thermal Decomposition of Hydrochloric Acid Treated Rice Husk and Properties of Its Product", J. Soc. Inorg. Mater., vol. 9, no. 301, pp. 505-510, June 2002. https://doi.org/10.11451/mukimate2000.9.505.
  26. [26] A. Salas, M. Ospina, S. Delvasto and R. Mejia de Gutierrez, “Study on the pozzolanic properties of silica obtained from rice husk by chemical and thermal process", Phys. Stat. Sol., vol. 4, no. 11, pp. 4311-4318, October 2007. https://doi.org/10.1002/pssc.200675924.
  27. [27] A. Salas, S. Delvasto, R. Mejia de Gutierrez and D. Lange, “Comparison of two processes for treating rice husk ash for use in high performance concrete", Cem. Conc. Res., vol. 39, pp. 773-778, September 2009. https://doi.org/10.1016/j.cemconres.2009.05.006
  28. [28] Q. Feng, H. Yamamichi, M. Shoya and S. Sugita, “Study of pozzolanic properties of Rice Husk Ash by hydrochloric acid pretreatment", Cem. Conc. Res., vol. 34, no. 3, pp. 521-526, March 2004. https://doi.org/10.1016/j.cemconres.2003.09.005
  29. [29] S. Mesa, D. Jaramillo, L. Uran and C. Velez, “Amorphous silica production from Colombian rice husk: demonstration in scaled-up process Products", Ing. Compet., vol. 26, no. 3, pp. e-21514396, November 2024. http://doi.org/10.25100/iyc.v26i3.14396.
  30. [30] M. De Souza and P. Batista, “Rice Hull-Derived Silica: Applications in Portland cement and Mullite Whiskers", Mater. Res., vol. 3, no. 2, pp. 25-30, April 2000. https://doi.org/10.1590/S1516-14392000000200005 .
  31. [31] U. Kalapathy, A. Proctor and J. Shultz, “A simple method for production of pure silica from rice hull ash", Bioresource Tech., vol. 73, pp. 257-262, July 2000. https://doi.org/10.1016/S0960-8524(99)00127-3.
  32. [32] S. Sona and S. P. Sangeetha, “Eco-friendly alternative activators derived from industrial wastes for the sustainable production of two-part geopolymer concrete at low cost", Constr. Build. Mater., vol. 467, pp. 140374, March 2025. https://doi.org/10.1016/j.conbuildmat.2025.140374.
  33. [33] A. Parrillo and G. Sánchez, “Coproduction of silicon nitride & oxynitride whiskers and precipitated silica from industrial rice husk ash”, Sustainable Mater. Technol., vol. 40, e00871, July 2024, doi: https://doi.org/10.1016/j.susmat.2024.e00871.
  34. [34] J.A. Santana Costa and CM. Paranhos, “Systematic evaluation of amorphous silica production from rice husk ashes”. J Clean Prod., vol. 192, pp. 88–697, August 2018, doi: https://doi.org/10.1016/j.jclepro.2018.05.028
  35. [35] U. Zulfiqar, T. Subhani and SW Husain., “Towards tunable size of silica particles from rice husk”. J Non Cryst. Solids., vol. 429, pp. 61–69, December 2015, doi: https://doi.org/10.1016/j.jnoncrysol.2015.08.037
  36. [36] M. A. Villaquirán-Caicedo and R. Mejía de Gutiérrez., “Synthesis of ceramic materials from ecofriendly geopolymer precursors”. Mater. Lett., vol. 230, pp 300 - 304, November 2018, doi: https://doi.org/10.1016/j.matlet.2018.07.128