Vol. 35 No. 1 (2022): Revista ION
Articles

Adsorption kinetics of diesel oil by in natura coconut fiber bioadsorbents (Cocus nucifera)

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  • Lailson de Sousa,
  • Harvey Alexander Villa-Vélez,
  • Paulo Henrique Coelho Leite
Lailson de Sousa
Universidade Federal do Maranhão, Departamento de Engenharia Química
Harvey Alexander Villa-Vélez
Universidade Federal do Maranhão, Departamento de Engenharia Química
Paulo Henrique Coelho Leite
Universidade Federal do Maranhão
DOI: https://doi.org/10.18273/revion.v35n1-2022008

Published 2022-11-01

Keywords

  • Adsorption,
  • Bioadsorbent.,
  • Kinetics,
  • Diesel,
  • Coconut fiber

How to Cite

de Sousa, L., Alexander Villa-Vélez, H., & Coelho Leite, P. H. (2022). Adsorption kinetics of diesel oil by in natura coconut fiber bioadsorbents (Cocus nucifera). Revista ION, 35(1), 117–131. https://doi.org/10.18273/revion.v35n1-2022008

Copyright (c) 2022 Lailson de Sousa, Harvey Alexander Villa-Vélez, Paulo Henrique Coelho Leite

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

Lignocellulosic bioadsorbents are commonly used in adsorption processes due to their characteristicss of
being environmentally friendly and economically profitable. In this work, an experimental design of 23 with a central point was applied to evaluated the efficiency of coconut mesocarp fibers (Cocus nucifera L.) as bioadsorbent for diesel. Thus, this research aims to determine the effect of the coconut mesocarp in the bioabsorption of diesel as a function of the concentration of fibers, granulometry and time of exposition.  Kinetics results were fitted using the models of pseudo-first-order, pseudo-second-order, intraparticle diffusion and Elovich. The highest sorption was observed for 125-250 µm granulometry, 45 min and 200 mg of fiber, which reached of 0.67 g of oil per gram of fiber. With this efficiency, for average contamination levels, 1 kg of fibers can be used to treat up to 10 m3 of effluent. A model of pseudo-second present the best fitted results. The activation energy was 210,13 J/mol with an Arrhenius constant equivalent to 60.47, revealing that the adsorption occurred by physisorption, through the surface diffusion of the adsorbate on the adsorbent.

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