Articles
Published 2016-12-15
Keywords
- Mathematical Models,
- Breakthrough Curve,
- Bioadsorbent,
- Cocoa Cob.
How to Cite
Lara, J., Tejada, C., Villabona, A., Arrieta, A., & Granados Conde, C. (2016). Adsorption of lead and cadmium in continuous of fixed bed on cocoa waste. Revista ION, 29(2). https://doi.org/10.18273/revion.v29n2-2016009
Abstract
The performance of the cocoa pod as adsorbent residual material heavy metals (Lead and Cadmium) in synthetic aqueous solution using a continuous fi xed bed system was evaluated. The experimental work was to determine the effect of bed height on the removal of these contaminants, keeping constant parameters such as pH, flow rate and initial concentration of metals. Adsorption tests showed a 91.32 and 87.80 % removal, respectively, for Pb and Cd elapsed after 4.5 h. Measuring concentrations in aqueous solution of metal ions was made by atomic adsorption. The adjustment of mathematical models evaluated Thomas, Dose-Response, Adams-Bohart and BDST (Bed-Depht Service Time analysis) was evaluated, to predict the dynamic behavior of the column and obtain the corresponding kinetic parameters. For models Thomas and dose response was observed that the values of the initial adsorption capacity, q0, decreased with increasing bed height, this may be due to a transfer slower mass, lower concentration and increased adsorption capacity, while models Adams-Bohart and BDST, volumetric adsorption capacity, N0, decreases with increasing column bioadsorbent. The results presented in this study indicate that cocoa waste can be used for the removal of heavy metals in waste water with satisfactory results.
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References
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[2] Ronda A, Martín-Lara MA,Calero M, Blázquez G. Analysis of the kinetics of lead biosorption using native and chemically treated olive tree pruning. Ecological Engineering. 2013;58:278–85.
[3] Tejada C, Villabona A, Ruiz V. Biomasa residual para remoción de mercurio y cadmio: una revisión. Ingenium, 2013;6(14):11-21.
[4] Lim AP, Aris AZ. Continuous fixed-bed column study and adsorption modeling: Removal of cadmium (II) and lead (II) ions in aqueous solution by dead calcareous skeletons. Biochemical Engineering Journal. 2014;87:50–61.
[5] Rao KS, Anad S, Venkateswarlu P. Modeling the kinetics of Cd(II) adsorption on Syzygium cumini L leaf powder in a fixed bed mini column. J. Ind. Eng. Chem. 2011;17:174–81.
[6] Bertagnolli C, Uhart A, Dupin JC, da Silva MGC, Guibal E, Desbrieres J. Biosorption of chromium by alginate extraction products from Sargassum filipendula: Investigation of adsorption mechanisms using X-ray photoelectron spectroscopy analysis. Bioresource Technology. 2014;164:264–9.
[7] Tarawou T, Young E. Intraparticle and Liquid film Diffusion Studies on the Adsorption of Cu2+ and Pb2+ Ions from Aqueous Solution using Powdered Cocoa Pod (Theobroma cacao). International Research Journal of Engineering and Technology (IRJET). 2015;2(8):236-43.
[8] Valencia JS, Castellar GC. Predicción de las curvas de ruptura para la remoción de plomo (II) en disolución acuosa sobre carbón activado en una columna empacada. Rev. Fac. Ing. Univ. Antioquia. 2013;66:141-58.
[9] Sotelo JL, Rodríguez A, Álvarez S, García J. Modeling and Elimination of Atenolol on Granular Activated Carbon in Fixed Bed Column. Int. J. Environ. Res. 2012;6(4):961-8.
[10] Villada-Villada Y, Hormaza A, Casis N. Uso de la cascarilla de arroz para la remoción de azul de metileno en columnas de lecho empacado. Revista Tecno Lógicas. 2014;17(33):43-54.
[11] Castellar GC, Cardozo BM, Suarez JF, Vega JE. Adsorción por lote y en una columna de lecho fijo del colorante B39 sobre carbón activado granular. Revista Prospectiva. 2013;11(1):66-75.
[12] Ardila C, Carreño S. Aprovechamiento de la cáscara de la mazorca de cacao como adsorbente (Tesis de pregrado]. Universidad Industrial de Santander, Bucaramanga. Colombia, 2011.
[13] Yu J, Wang L, Chi R, Zhang Y, Xu Z, Guo J. Competitive adsorption of Pb2+ and Cd2+ on magnetic modified sugarcane bagasse prepared by two simple steps. Applied Surface Science. 2013;268:163–70.
[14] Long Y, Lei D, Ni J, Ren Z, Chen C, Xu H. Packed bed column studies on lead (II) removal from industrial wastewater by modified Agaricus bisporus. Bioresource Technology. 2014;152:457-63.
[15] Khraisheh MAM, Al-degs YS, Mcminn WAM. Remediation of wastewater containing heavy metals using raw and modified diatomite. Chem. Eng. 2004;99:177-84.
[16] Thomas HC. Heterogeneous ion exchange in a flowing system. J. Am. Chem. Soc. 1944;66(10):1664–6.
[17] Morales C, Kan CC, Dalida ML, Pascua C, Wan WW. Fixed–bed column studies on the removal of copper using chitosan immobilized on bentonite. Carbohydr. Polym. 2011;83(2):697–704.
[18] Ding D, Han R, Xu Y, Zou W, Wang Y, Li Y, Zou L. Use of rice husk for the adsorption of congo red from aqueous solution in column mode. Bioresour. Technol. 2007;99(8):2938-46.
[19] Rajput MS, Sharma AK, Sharma, S,Verma S. Removal of lead (II) from aqueous solution using low cost abundantly available adsorbents: A. IJCS. 2015;3(1):09-14.
[20] Nwabanne JT, Igbokwe PK. Comparative study of Lead (II) removal from aqueous solution using different adsorbents. International Journal of Engineering Research and Applications. 2012;2(4):1830-8.
[21] Li TT, Liu YG, Peng QQ, Hu XJ, Liao T, Wang H, Lu M. Removal of lead (II) from aqueous solution with ethylenediamine-modified yeast biomass coated with magnetic chitosan microparticles: Kinetic and equilibrium modeling. Chem. Eng. J. 2013;214:189-97.
[22] Calero M, Hernáinz F, Blázquez G, Tenorio G, Martín–Lara MA. Study of Cr (III) bioroption in a fixed–bed column. J. Hazard. Mater. 2009;171(1-3):886–93.
[23] Han R, Wang Y, Zhao X, Xie F, Cheng J, Tang M. Adsorption of methylene blue by phoenix tree leaf powder in a fixed-bed column: experiments and prediction of breakthrough curves. Desalination. 2009;245(1-3):284-97.
[24] Abdelwahab O, Fouad YO, Amin NK, Mandor H. Kinetic and thermodynamic aspects of cadmium adsorption onto raw and activated guava (Psidium guajava) leaves. Environ. Prog. Sustainable Energy. 2015;34:351–8.
[25] Kyzas G, Deliyanni E, Matis K. Activated carbons produced by pyrolysis of waste potato peels: Cobalt ions removal by adsorption. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2016;490:74-83.
[26] Dokeos KM, Khan EM. Equilibrium, kinetic and diffusion mechanism of Cr (VI) adsorption onto activated carbon derived from wood apple shell. Arabian Journal of Chemistry, In Press, Corrected Proof, Available online 3 August 2012.
[27] Yuan XZ, Meng YT, Zeng GM, Fang YY, Shi JG. Evaluation of tea-derived biosurfactant on removing heavy metal ions from dilute wastewater by ion flotation. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2008;317(1–3):256–61.
[28] Dávila N. Caracterización del proceso de Biosorción de metales pesados mediante residuos sólidos de café (Tesis de Doctorado) en Ciencias con orientación en procesos sustentables. Nuevo León, México: Universidad Autónoma Nuevo; 2012.
[29] Odoemelam SA, Iroh CU, Igwe JC. Copper (II), cadmium (II) and lead (II) adsorption kinetics from aqueous metal solutions using chemically modified and unmodified cocoa pod husk (Theobroma cacao) waste biomass.Research Journal of Applied Sciences. 2011;6(1):44-52.
[30] Bulgariu D, Bulgariu L. Potential use of alkaline treated algae waste biomass as sustainable biosorbent for clean recovery of Cadmium(II) from aqueous media: batch and column studies. Journal of Cleaner Production. 2016;112: 4525-33.
[31] Inglezakis VJ, Grigoropoulou HP. Modeling of ion exchange of Pb2+ in fixed beds of clinoptilolite. Microp.Mesop. Mater.2003;61:273-82.
[32] Acosta I, López V, Coronado E, Cárdenas JF, Martínez VM. Remoción de Cromo (VI) en Solución Acuosa por la Biomasa de la Cáscara de Tamarindo (Tamarindus indica). Biotecnología. 2010;15(3):11-23.