Published 2016-12-15
Keywords
- Urea,
- Ethanol,
- Gravimetric Method,
- Solubility
How to Cite
Abstract
This paper deals with the solubility of urea in ethanol-water mixtures in mole fractions of ethanol between 0.0901 and 1.000 at temperatures ranging from 278.1 to 333.1K. The investigation of solubility contributes to research in many others fields of study in chemical engineering, since there are several studies where the solubility of urea and its behavior in solution influence the system. The experiment was carried out at constant temperature, stirring for 2 hours and then leaving the solution at rest for 2 hours. After collecting the data, the solubility of urea was calculated based on the gravimetric method. The experimental results obtained were correlated with the temperature of the solvents using three equations based on the literature. The three models demonstrated results in line with the experimental data. It was observed that adding ethanol to the water decreased urea solubility in all cases. The differences between the predicted and the experimental values were on average 4.7%.
Downloads
References
[2] Voskov AL, Babkina TS, Kuznetsov AV, Uspenskaya IA. Phase Equilibria in the Urea— Biuret—Water System. J. Chem. Eng. Data. 2012;57(11):3225-32.
[3] Glibert PM, Trice TM, Michael B, Lane L. Urea in the tributaries of the Chesapeake and coastal bays of Maryland Water Air Soil Pollut. 2005;160:229–43.
[4] Francis PS, Lewis SW, Lim KF. Analytical methodology for the determination of urea: current practice and future Anal. Chem. 2002;21:389–400.
[5] Józwiak M, Tyczynska M, Bald A. Viscosity of Urea in the Mixture of N,N-Dimethylformamide and Water. J. Chem. Eng. Data. 2013;58(2):217- 24.
[6] Hu Y, Chen X, Yang W, Guan J. Measurement and correlation of urea l-tartaric acid in aqueous ethanol solution. Thermochimica Acta. 2009;484: 38-40.
[7] Lim J, Jang S, Cho HK, Shin MS, Kim H. Solubility of salicylic acid in pure alcohols at different temperatures J. Chem. Thermodynamics. 2013;57:295-300.
[8] Tang J, Mu R, Zang B. Fan X. Solubility of urea phosphate in water + phosphoric acid from (277.00 to 354.50)K. J. Chem. Eng. Data. 2007;52:1179-181.
[9] Loeser E, DelaCruz M, Madappalli V. Solubility of Urea in Acetonitrile—Water Mixtures and Liquid—Liquid Phase Separation of UreaSaturated Acetonitrile—Water Mixtures. J. Chem. Eng. Data. 2011;56(6):2909-13.
[10]Oliveira MLN, Malagoni RA, Franco Júnior MR. Fluid Phase Equilibria. Solubility of citric acid in water, ethanol, n-propanol and in mixtures of ethanol + water. 2013;352:110-13.
[11] Oliveira MLN, Malagoni RA, Fehr M, Franco Júnior MR. Obtaining Solubility Data from a Liquid-Liquid Equilibrium Cell. Chem. Eng. Comm. 2008;195:1076-084.
[12]Wang Q, Xu H, Li X. Solubilities of Terephthalic Acid, Phthalic Acid, and Isophthalic Acid in Tetrahydrofuran, Cyclohexanone, 1,2-Diethoxyethane, and Acetophenone J. Chem. Eng. Data. 2009;54(11):3130-132.
[13]Lee FM, Lahti LE. Solubility of urea in wateralcohol mixtures. J. Chem. Eng. Data. 1972;17(3)304-06.
[14]Lee FM, Lahti LE, Stoops CE. Solution properties of urea-alcohol-water mixtures. J. Chem. Eng. Data. 1976;21(1):36-40.
[15]Prausnitz JM, Lichtenthaler RN, de Azevedo EG. Molecular Thermodynamics of Fluid Phase Equilibria. Third edition. Prentice Hall International Series in the Physical and Chemical Engineering Sciences, 1999.
[16]Ran Y, He Y, Yang G, Johnson JLH, Yalkowosky SH. Estimation of aqueous solubility of organics compounds by using the general solubility equation. Chemosphere 2002;48:487-509.
[17]Bernardes EA, Brunetto RS, Franco Jr MR. In: 15th COBEQ – Congresso Brasileiro de Engenharia Química, 2004, Curitiba/Brazil. Proceedings of the 15th COBEQ, 2004. p. 1-8.
[18]Orbey H, Sandler SI. Relative measurements of activity coefficients at infinite dilution by gas chromatography. Ind. Eng. Chem. Res.1991;30(8):2006-011.
[19]Reddy SN, Madras G. Mixture solubilities of nitrobenzoic acid isomers in supercritical carbon dioxide. Journal of Supercritical Fluids. 2012;70:66-74.
[20]Yaws CL, Lin X, Bu L. The water solubility of naphtenes Chem. Eng. 1994;101:119-28.
[21]Yaws CL, Pan X, Lin X. Water Solubility Data for 151 Hydrocarbons. Chem. Eng.1993;100:108-11.
[22]Buchowski H, Ksiazczak A, Pietrzyk S. Solvent activity along a saturation line and solubility of Hydrogen-Bonding solids. J. Phys. Chem. 1980;84:975-79.