Artículos
Tratamiento de aguas residuales producidas en el proceso de remojo en curtiembres empleando ozono y hierro como catalizador
Rafael Nikolay Agudelo Valencia- María Claudia Caicedo Jiménez
Publicado 2021-09-13
Palabras clave
- Agua residual de curtiembre,
- Catalizador,
- Hierro,
- Ozono,
- pH
Cómo citar
Rodríguez Agudelo, K. T., Agudelo Valencia, R. N., & Caicedo Jiménez, M. C. (2021). Tratamiento de aguas residuales producidas en el proceso de remojo en curtiembres empleando ozono y hierro como catalizador. Revista ION, 34(2), 105–113. https://doi.org/10.18273/revion.v34n2-2021010
Resumen
Se analizó el tratamiento de las aguas residuales generadas en el proceso de remojo en curtiembres por medio de oxidación con ozono y hierro ferroso para catalizar la mineralización de materia orgánica (medida en términos de DQO). Los ensayos fueron desarrollados en modo discontinuo y tiempo de reacción constante. El agua residual para la realización de ensayos fue suministrada por una empresa de curtido de pieles ubicada en el municipio de Villapinzón, Colombia. Se empleó un diseño experimental factorial del tipo 32, los factores experimentales fueron el pH inicial del agua residual (4,7 y 10) y la dosis de Fe2+ en el agua y las variables de respuesta fueron los porcentajes de remoción de turbiedad y DQO. Los resultados señalan que la máxima remoción de turbiedad se logra a pH alcalino y en el caso de DQO, la mayor remoción fue de 92,13 % y se logra para pH 10 y 10 mgL-1 de dosis de Fe2+. El tiempo de reacción empleado para cada ensayo fue de 2 horas de modo que la dosis de ozono fue de 4 gL-1 y el consumo de energía fue de 0,021 kWhg-1DQOremovida.
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Referencias
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[2] Elabbas S, Ouazzani N, Mandi L, Berrekhis F, Perdicakis M, Pontvianne S, et al. Treatment of highly concentrated tannery wastewater using electrocoagulation: influence of the quality of aluminium used for the electrode. J. Hazard.
Mater. 2016; 319: 69-77.
[3] Lazo Cuentas EA. Evaluación De La Contaminación Ambiental Generada Por Efluentes Industriales En El Proceso
Productivo De Una Curtiembre De Mediana Capacidad Del Parque Industrial De Rio Seco, Arequipa. Arequipa, Perú; 2017.
[4] Borba FH, Seibert D, Pellenz L, Espinoza FR, Borba CE, Módenes AN, et al. Desirability function applied to the optimization of the Photoperoxi-Electrocoagulation process conditions in the treatment of tannery industrial
wastewater. J. Water Process Eng. 2018; 23: 207-16.
[5] Varilla J, Díaz F. Tratamiento de aguas residuales mediante lodos activados a escala laboratorio. Rev. de Tecnol. 2008; 7(2): 21-28.
[6] Velásquez S, Giraldo D, Cardona N. Reciclaje de residuos de cuero: una revisión de estudios experimentales. Inf. Tec. 2015; 79(2): 188-98.
[7] Das C, DasGupta S, De S. Treatment of soaking effluent from a tannery using membrane separation processes. Desalineation. 2007; 216(1-3): 160-73.
[8] Sawalha H, Alsharabaty R, Sarsour S, Al- Jabari M. Wastewater from leather tanning and processing in Palestine: Characterization and management aspects. J. Environ. Manage. 2019; 251: 109596.
[9] Lofrano G, Meric S, Emel G, Orhon D. Chemical and biological treatment technologies for leather tannery chemicals and wastewaters: A review. Sci.Total Environ. 2013; 461-462: 265-81.
[10] Hashem A, Nur-A-Tomal S, Bushra SA. Oxidation-coagulation-filtration processes for the reduction of sulfide from the hair burning liming wastewater in tannery. J. Cleaner Prod. 2016; 127: 339-42.
[11] Kumari V, Yadav A, Haq I, Kumar S, Bharagava RN, Singh SK, et al. Gentoxicity evaluation of tannery effluent treated with newly isolated hexavalent chromium reducing Bacillus Cereus. J. of Environ. Manage. 2016; 183(1): 204-11.
[12] da Fontoura JT, Rolim GS, Farenzena M, Farenzena M, Gutterrez. Influence of light intensity and tannery wastewater concentration on biomass production and nutrientremoval by microalgae Scenedesmus sp. Process Saf.
Environ. Prot. 2017; 111: 355-62.
[13] Shakir L, Ejaz S, Ashraf M, Qureshi NA, Iltaf Im, Javeed A. Ecotoxicological risks associated with tannery effluent wastewater. Environ. Toxicol. Pharmacol. 2012; 34(2): 180-91.
[14] Maharaja P, Magthalian C, Mahesh M, Sunkapur LK, Swarnalatha S, Sekaran G. Treatment of tannery saline wastewater by using effective immobilized protease catalyst produced from salt tolerant Enterococcus feacalis. J. Environ. Chem. Eng. 2017; 5(2): 2042-55.
[15] Papageorgiou A, Stylianou SK, Kaffes P, Zouboulis AI, Voutsa D. Effects of ozonation pretreatment on natural organic matter and wastewater derived organic matter e Possible implications on the formation of ozonation by products. Chemosphere. 2017; 170: 33-40.
[16] Cerón P. Estudio de un sistema físico-químico a escala prototipo de tratamiento de aguas residuales provenientes de una curtiembre. (Tesis de grado). Quito, Ecuador: Univesidad San Francisco de Quito; 2011.
[17] Lefebvrea O, Vasudevan N, Torrijos M, Thanasekaran K, Moletta R. Anaerobic digestion of tannery soak liquor with an aerobic post-treatment. Water Res. 2006; 40(7): 1492-1500.
[18] Sekar S, Sivaprakasam S, Mahadevan. Investigations on ultraviolet light and nitrous acid induced mutations of halotolerant bacterial strains for the treatment of tannery soak liquor. Int. Biodeterior. Biodegrad. 2009; 63(2): 176-81.
[19] Pounsamy M, Somasundaram S, Palanivel S, Balasubramani R, Chang SW, Nguyen DD, Ganesan S, et al. A novel protease-immobilized carbon catalyst for the effective fragmentation of proteins in high-TDS wastewater generated in tanneries: Spectral and electrochemical studies. Environ. Res. 2019; 172: 408-19.
[20] Asghar A, Raman AAA, Daud WMAW. Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: A review. J. Cleaner Prod. 2015; 87: 826–38.
[21] Huang Y, Luo M, Xu Z, Zhang D, Li L. Catalytic ozonation of organic contaminants in petrochemical wastewater with iron-nickel foam as catalyst. Sep. Purif. Technol. 2019; 211: 269–278.
[22] Ribeiro AR, Nunes OC, Pereira MR, Silva AMTT. An overview on the advanced oxidation processes applied for the treatment of water pollutants defined in the recently launched Directive 2013/39/EU. Environ. 2015; 75: 33–51.
[23] Wu J, Ma L, Chen Y, Cheng Y, Liu Y, Zha X. Catalytic ozonation of organic pollutants from bio-treated dyeing and finishing wastewater using recycled waste iron shavings as a catalyst: Removal and pathways. Water Res 2016; 92:140–48.
[24] Giaccherini F, Munz G, Dockhorn T, Lubello C, Rosso D. Carbon and energy footprint analysis of tannery wastewater treatment: A Global overview. Water Resour. Ind. 2017; 17: 43–52.
[25] Quintero GP, Quijano A, Melendez I. Efecto Genotoxico del agua residual de la curtiembre de San Faustino-Norte de Santander Colombia. Revista Colombiana de Tecnol. Av. 2018; 2(32): 8-16.
[26] Castañeda YL, Vargas R, Césare MF, Visitación L. Evaluación y tratamiento de efluentes del remojo convencional y enzimático de pieles, por precipitación de proteínas y coagulación. Rev. Soc. Quím. Perú, 2016; 82(4): 440-53.
[27] American Public Health Association, American Water Works Association, water environment federation, Standard methods for the examination of water and wastewater. New York, USA; 2017.
[28] Sun Y, Li J, Huang T, Guan X. The influences of iron characteristics, operating conditions and solution chemistry on contaminants removal by zero-valent iron: A review. Water Res. 2016; 100: 277–295.
[29] Huang Y, Jiang J, Ma L, Wang Y, Liang M, Zhang Z, et al. Iron foam combined ozonation for enhanced treatment of pharmaceutical wastewater. Environ. Res. 2020 ; 183 : 109205.
[30] Ulson, SMDAG, Bonilla KAS, de Souza AAU. Removal of COD and color from hydrolyzed textile azo dye by combined ozonation and biological treatment. J. Hazard. Mater. 2010; 179: 35-42.