Artigos
Estudos de investidores para produção de furfural-etanol e placas a partir do bagaço de cana de çúcar
Marlén Morales-Zamora- Nestor Ley-Chong
- Ana Celia de Armas Martinez
- Erenio González-Suárez
Publicado 2021-08-13
Palavras-chave
- Bagaço,
- Furfural,
- Etanol,
- Reconversão,
- Investimento
Como Citar
Morales-Zamora, M., Mesa-Garriga, L., Ley-Chong, N., de Armas Martinez, A. C., Acosta-Martinez, D. R., & González-Suárez, E. (2021). Estudos de investidores para produção de furfural-etanol e placas a partir do bagaço de cana de çúcar. REVISTA ION, 34(2), 17–29. https://doi.org/10.18273/revion.v34n2-2021002
Resumo
Atualmente, aproveitem as facilidades da indústria para modificar, reanimação ou reconversão suas produções, é importante para a redução dos custos de investimento e o aumento da disponibilidade das
plantas. Nesse sentido, a investigação visa a realização de um estudo prévio com investidor, em um complexo sucroalcooleiro com usinas de derivados instaladas, para a produção conjunta de furfural, etanol e placas a partir do bagaço, considerando a reconversão no parque industrial. Para tanto, partimos das modificações e resultados obtidos por Mesa [1], na etapa de fracionamento do bagaço para a obtenção
de glicose, xilose e furfural, e a utilização de resíduos na planta de papelão Morales-Zamora [2]. Os estudos de pré-viabilidade econômica são realizados para as usinas separadamente e com a proposta de integração e reconversão. Na análise integrada, é proposto um planejamento fatorial 24 considerando a influência das variáveis fluxo da cana, fluxo do etanol, confiabilidade e preços, para um cenário otimista de preços e capacidades. Os resultados econômicos são favorecidos por aumentos no escoamento de etanol, com menor escoamento de cana, considerando a confiabilidade com a reconversão e com aumentos no preço do açúcar. A reconversão para a obtenção de açúcar, eletricidade, furfural, placas e etanol possibilitará o resgate de usinas e equipamentos instalados, o que impactaria a minimização de investimentos, bem como um desenvolvimento prospectivo de adaptação da indústria açucareira ao conceito de biorrefinaria.
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Referências
[1] Mesa L, Morales M, González E, Cara C, Romero I, Castro E, Mussato S. Restructuring the processes for furfural and xylose production from sugarcane bagasse in a biorefinery concept for ethanol production. Chemical Engineering and Processing: Process Intensification. Chemical Engineering and Processing 2014;85:196-202.
[2] Morales-Zamora M, González-Suárez E, Mesa-Garriga L. Advances in obtaining fibreboards from lignocellullosic residual mixtures of bagasse. Afinidad. 2016;73(575):205-209.
[3] Gálvez LO. La producción diversificada de la agroindustria de la caña de azúcar. Manual de los derivados de la caña de azúcar. 3 ed. La Habana, Cuba. Editorial ICIDCA; 2000.
[4] González E. Asimilación (Adopción) y reconversión de tecnologías para la producción de Biocombustibles. España, CYTED Ediciones cooperativas; 2008.
[5] Kaylen M, Van D, DL. Choi YS, Economic feasibility of producing ethanol from lignocellulosic feedstock. Bioresorurce Technology. 2000; 72(1):19-32.
[6] Wyman CE, Dale BE, Elander RT, Holtzapple M, Ladisch MR and Lee YY. Comparative sugar
recovery data from laboratory scale application of leading pretreatment technologies to corn
stover. Biores Technol. 2005;96(18):2026-2032.
[7] Caye M. Drapcho, Nghiem Nhuan, Terry H. Walker. Biofuels Engineering Process Technology. The McGraw-Hill Companies. 2008. DOI: 10.1036/0071487492.
[8] Zhou, Xi; Xu, Yong. Integrative process for sugarcane bagasse biorefinery to co-produce xylooligosaccharides and gluconic acid. Bioresource Technology. 2019;282: 81-87.
[9] Morales M, Verelst H, Mesa L, and Gonzales E. Simulation of furfural production process
for revamping with ethanol technology from lignocellulosic residuals, Chemical Engineering Transactions. 2010; 21: 967- 972. DOI:10.3303/CET1021162.
[10] Candido RG, Gonçalves AR. Evaluation of two different applications for cellulose isolated
from sugarcane bagasse in a biorefinery concept. Industrial Crops and Products. 2019;142:111616.
[11] Sakdaronnarong C, Pipathworapoom W, Vichitsrikamol T, Sema T, Posoknistakul P, Koo-amornpattana W, Laosiripojana N. Integrative process for a sugarcane bagasse biorefinery to produce glucose, bio-oil and carbon microspheres. Process Safety and Environmental Protection. 2018;116:1-13.
[12] Hsu TA. Pretreatment of biomass. Handbook on bioethanol: production and utilization. USA, Ed. Taylor & Francis; 1996. p.179-212.
[13] Sun Y, Cheng J. Hydrolysis of lignocellulosic materials for ethanol production: a review. Bioresource technology. 2002;83(1):1-11.
[14] Larsson M, Galbe M, Zacchi G. Recirculation of process water in the production of ethanol from softwood. Bioresource Technology. 1997;60(2):143-151.
[15] Lenihan P, Orozco A, O’Neill E, Ahmad MNM, Rooney DW, Walker GM. Dilute acid hydrolysis of lignocellulosic biomass. Chemical Engineering Journal. 2010; 156: 395–403.
[16] Singh A. Kumudeswar D, and Durlubh K. Sharma. Integrated Process for Production of Xylose, Furfural, and Glucose from Bagasse by Two-step Acid Hydrolysis. Ind. Eng. Chem. Prod. Res. Dev. 1984; 23(2):257-262.
[17] Piñeros-Castro Y, Amparo Velasco G, Proaños J, Cortes W, Ballesteros I. Producción de azúcares fermentables por hidrólisis enzimática de cascarilla de arroz pretratada mediante explosión con vapor. rev.ion.2011;24(2):23-28.
[18] Pires Nogueira D, Ferreira Rosa PR, Seolatto AA, Galeano Suarez CA, Ferreira Freitas F. Saccharification of Orange Bagasse Pretreated with Calcium Hydroxide using an enzymatic blend Diluted Hydrochloric Acid. rev. ion. 2019;32(1):75-85. doi:10.18273/revion. v32n1-2019007
[19] Mesa L, González E, Cara C, Ruiz E, Romero I. Castro E. Preliminary evaluation of organosolv pre-treatment of sugar cane bagasse for glucose production: Application of 23 experimental design. Appl Energy. 2010;87: 109-114.
[20] Mesa L, González E, Cara C, Ruiz E, Castro E, Mussatto SI. An approach to optimization of enzymatic hydrolysis from sugarcane bagasse based on organosolv pretreatment. Journal of Chemical Technology & Biotechnology. 2010;85(8):1092-1098.
[21] Aguilar R, Ramírez JA, Garrote G. Kinetic study of the acid hydrolysis of sugar cane bagasse. J. Food Engineering. 2002;55:309.
[22] Cheng KK, Cai BY, Zhang JA, Ling HZ, Zhou YJ, Ge JP, Xu JM. Sugarcane bagasses hemicellulose hydrolysate for ethanol production by acid recovery process. Biochem. Eng. J. 2008;38(1):105-109.
[23] Linde M, Jakobsson E, Galbe M, Zacchi G. Steam pretreatment of dilute H2SO4- impregnated wheat straw and SSF with low yeast and enzyme loadings for bioethanol production. Biomass and Bioenergy. 2008;32(4):326-332.
[24] Xu C, Zhang J, Zhang Y, Guo Y, Xu H, Xu J, Wang Z. Enhancement of high-solids enzymatic hydrolysis efficiency of alkali pretreated sugarcane bagasse at low cellulase dosage by fed-batch strategy based on optimized accessory enzymes and additives.
Bioresource technology. 2019;292:121993.
[25] Chandel AK, Garlapati VK, Singh AK, Antunes FAF, da Silva, SS. The pathforward for lignocellulose biorefineries: Bottlenecks, Solutions, and perspective on commercialization, BioresourceTechnology. 2018;264:370-38. doi: https://doi.org/10.1016/j.
biortech.2018.06.004
[26] Morales-Zamora M, Espino-Leal I, Mesa-Garriga L, Acosta-Martínez D, González- Suárez E, Castro-Galiano E. Evaluación de residuales de la hidrólisis ácida del bagazo como productos de alto valor añadido. Afinidad LXVIII. 2011;68(556).
[27] Morales-Zamora M, González-Suárez E. Reliability Assessment on a Diversified Industry from the Revamp of its Facilities. Tecnología Química. 2017;37(1):5-15. DOI: http://dx.doi.org/10.1590/2224-6185.2017.1.1
[28] Morales-Zamora M, de Armas A, Mesa- Garriga L, Acosta Martínez D, González- Suárez E. Advances in the use of the hydrolyzed liquor of bagasse in the fermentation of sugar mixtures. Afinidad. 2018; 75(581):61-65.
[29] Murcia-P JF, Ardila-A AN, Barrera Zapata R. Producción de etanol a partir de piñas de rechazo de cultivos del Chocó. rev. ion. 2020;33(1):47-56. doi:10.18273/revion.v33n1- 2020005
[2] Morales-Zamora M, González-Suárez E, Mesa-Garriga L. Advances in obtaining fibreboards from lignocellullosic residual mixtures of bagasse. Afinidad. 2016;73(575):205-209.
[3] Gálvez LO. La producción diversificada de la agroindustria de la caña de azúcar. Manual de los derivados de la caña de azúcar. 3 ed. La Habana, Cuba. Editorial ICIDCA; 2000.
[4] González E. Asimilación (Adopción) y reconversión de tecnologías para la producción de Biocombustibles. España, CYTED Ediciones cooperativas; 2008.
[5] Kaylen M, Van D, DL. Choi YS, Economic feasibility of producing ethanol from lignocellulosic feedstock. Bioresorurce Technology. 2000; 72(1):19-32.
[6] Wyman CE, Dale BE, Elander RT, Holtzapple M, Ladisch MR and Lee YY. Comparative sugar
recovery data from laboratory scale application of leading pretreatment technologies to corn
stover. Biores Technol. 2005;96(18):2026-2032.
[7] Caye M. Drapcho, Nghiem Nhuan, Terry H. Walker. Biofuels Engineering Process Technology. The McGraw-Hill Companies. 2008. DOI: 10.1036/0071487492.
[8] Zhou, Xi; Xu, Yong. Integrative process for sugarcane bagasse biorefinery to co-produce xylooligosaccharides and gluconic acid. Bioresource Technology. 2019;282: 81-87.
[9] Morales M, Verelst H, Mesa L, and Gonzales E. Simulation of furfural production process
for revamping with ethanol technology from lignocellulosic residuals, Chemical Engineering Transactions. 2010; 21: 967- 972. DOI:10.3303/CET1021162.
[10] Candido RG, Gonçalves AR. Evaluation of two different applications for cellulose isolated
from sugarcane bagasse in a biorefinery concept. Industrial Crops and Products. 2019;142:111616.
[11] Sakdaronnarong C, Pipathworapoom W, Vichitsrikamol T, Sema T, Posoknistakul P, Koo-amornpattana W, Laosiripojana N. Integrative process for a sugarcane bagasse biorefinery to produce glucose, bio-oil and carbon microspheres. Process Safety and Environmental Protection. 2018;116:1-13.
[12] Hsu TA. Pretreatment of biomass. Handbook on bioethanol: production and utilization. USA, Ed. Taylor & Francis; 1996. p.179-212.
[13] Sun Y, Cheng J. Hydrolysis of lignocellulosic materials for ethanol production: a review. Bioresource technology. 2002;83(1):1-11.
[14] Larsson M, Galbe M, Zacchi G. Recirculation of process water in the production of ethanol from softwood. Bioresource Technology. 1997;60(2):143-151.
[15] Lenihan P, Orozco A, O’Neill E, Ahmad MNM, Rooney DW, Walker GM. Dilute acid hydrolysis of lignocellulosic biomass. Chemical Engineering Journal. 2010; 156: 395–403.
[16] Singh A. Kumudeswar D, and Durlubh K. Sharma. Integrated Process for Production of Xylose, Furfural, and Glucose from Bagasse by Two-step Acid Hydrolysis. Ind. Eng. Chem. Prod. Res. Dev. 1984; 23(2):257-262.
[17] Piñeros-Castro Y, Amparo Velasco G, Proaños J, Cortes W, Ballesteros I. Producción de azúcares fermentables por hidrólisis enzimática de cascarilla de arroz pretratada mediante explosión con vapor. rev.ion.2011;24(2):23-28.
[18] Pires Nogueira D, Ferreira Rosa PR, Seolatto AA, Galeano Suarez CA, Ferreira Freitas F. Saccharification of Orange Bagasse Pretreated with Calcium Hydroxide using an enzymatic blend Diluted Hydrochloric Acid. rev. ion. 2019;32(1):75-85. doi:10.18273/revion. v32n1-2019007
[19] Mesa L, González E, Cara C, Ruiz E, Romero I. Castro E. Preliminary evaluation of organosolv pre-treatment of sugar cane bagasse for glucose production: Application of 23 experimental design. Appl Energy. 2010;87: 109-114.
[20] Mesa L, González E, Cara C, Ruiz E, Castro E, Mussatto SI. An approach to optimization of enzymatic hydrolysis from sugarcane bagasse based on organosolv pretreatment. Journal of Chemical Technology & Biotechnology. 2010;85(8):1092-1098.
[21] Aguilar R, Ramírez JA, Garrote G. Kinetic study of the acid hydrolysis of sugar cane bagasse. J. Food Engineering. 2002;55:309.
[22] Cheng KK, Cai BY, Zhang JA, Ling HZ, Zhou YJ, Ge JP, Xu JM. Sugarcane bagasses hemicellulose hydrolysate for ethanol production by acid recovery process. Biochem. Eng. J. 2008;38(1):105-109.
[23] Linde M, Jakobsson E, Galbe M, Zacchi G. Steam pretreatment of dilute H2SO4- impregnated wheat straw and SSF with low yeast and enzyme loadings for bioethanol production. Biomass and Bioenergy. 2008;32(4):326-332.
[24] Xu C, Zhang J, Zhang Y, Guo Y, Xu H, Xu J, Wang Z. Enhancement of high-solids enzymatic hydrolysis efficiency of alkali pretreated sugarcane bagasse at low cellulase dosage by fed-batch strategy based on optimized accessory enzymes and additives.
Bioresource technology. 2019;292:121993.
[25] Chandel AK, Garlapati VK, Singh AK, Antunes FAF, da Silva, SS. The pathforward for lignocellulose biorefineries: Bottlenecks, Solutions, and perspective on commercialization, BioresourceTechnology. 2018;264:370-38. doi: https://doi.org/10.1016/j.
biortech.2018.06.004
[26] Morales-Zamora M, Espino-Leal I, Mesa-Garriga L, Acosta-Martínez D, González- Suárez E, Castro-Galiano E. Evaluación de residuales de la hidrólisis ácida del bagazo como productos de alto valor añadido. Afinidad LXVIII. 2011;68(556).
[27] Morales-Zamora M, González-Suárez E. Reliability Assessment on a Diversified Industry from the Revamp of its Facilities. Tecnología Química. 2017;37(1):5-15. DOI: http://dx.doi.org/10.1590/2224-6185.2017.1.1
[28] Morales-Zamora M, de Armas A, Mesa- Garriga L, Acosta Martínez D, González- Suárez E. Advances in the use of the hydrolyzed liquor of bagasse in the fermentation of sugar mixtures. Afinidad. 2018; 75(581):61-65.
[29] Murcia-P JF, Ardila-A AN, Barrera Zapata R. Producción de etanol a partir de piñas de rechazo de cultivos del Chocó. rev. ion. 2020;33(1):47-56. doi:10.18273/revion.v33n1- 2020005