v. 35 n. 2 (2022): Revista ION
Artigos

Gaseificação Catalítica e Autotérmica de Resíduos Biomassicos a banco escala: construção e otimização.

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  • Lina Garcia Peña,
  • Misael Cordoba Arroyo,
  • Liza Dosso,
  • Carlos Roman Vera,
  • Juan Carlos Casas Zapata,
  • Alfonso Enrique Ramírez Sanabria,
  • Mariana Busto,
  • Juan Badano
Misael Cordoba Arroyo
Instituto de Investigaciones en catálisis y petroquímica
Liza Dosso
Instituto de Investigaciones en Catálisis y Petroquímica (INCAPE)
Carlos Roman Vera
Instituto de Investigaciones en Catálisis y Petroquímica (INCAPE)
Juan Carlos Casas Zapata
Instituto de Investigaciones en Catálisis y Petroquímica (INCAPE)
Alfonso Enrique Ramírez Sanabria
Grupo de Catálisis, Departamento De Química, Universidad Del Cauca
Mariana Busto
Instituto de Investigaciones en Catálisis y Petroquímica (INCAPE)
Juan Badano
Instituto de Investigaciones en Catálisis y Petroquímica (INCAPE)
DOI: https://doi.org/10.18273/revion.v35n2-2022007

Publicado 2022-12-05

Palavras-chave

  • Gaseificação,
  • Catálise,
  • Alcatrão,
  • Biomassa,
  • gás de síntese

Como Citar

Garcia Peña, L., Cordoba Arroyo, M., Dosso, L., Vera, C. R., Casas Zapata, J. C., Ramírez Sanabria, A. E. ., Busto, M., & Badano, J. (2022). Gaseificação Catalítica e Autotérmica de Resíduos Biomassicos a banco escala: construção e otimização. REVISTA ION, 35(2), 83–99. https://doi.org/10.18273/revion.v35n2-2022007

Copyright (c) 2022 Lina Garcia Peña, Misael Cordoba Arroyo, Liza Dosso, Carlos Roman Vera, Juan Carlos Casas Zapata, Alfonso Enrique Ramírez Sanabria, Mariana Busto, Juan Badano

Creative Commons License
Este trabalho está licenciado sob uma licença Creative Commons Attribution 4.0 International License.

Resumo

Neste trabalho foi construído e otimizado o dimensionamento de um sistema de gaseificação de resíduos biomássicos (serragem de pinus). O sistema consta de uma unidade de alimentação (canoura e parafuso), um reator autotérmico de leito fluidizado e unidade de acondicionamento de gases (ciclone e esfriamento). No reator foram avaliados 2 catalisadores de baixo custo: um mineral natural (dolomita) e resíduo de pirólise comparados com um sólido inerte (areia). Os catalisadores e a biomassa caracterizassem por diferentes tecnicas: ICP, BET, TGA, CHONS, entre outras. Na otimização do processo foram estudados diferentes parâmetros: tamanho de partícula de biomassa, fluxo mássico de alimentação, agentes gasificantes e perfis de temperatura. Os ensaios mostraram um ótimo funcionamento com um tamanho de biomassa na faixa de 0.50-0.85 mm, um fluxo mássico de alimentação de 0.840 kg/h, e uma relação de equivalência entre mistura de agentes gasificantes (ar /ou vapor de água) e alimentação de 0.35-0.45 com temperaturas de equilíbrio de 650 y 750ºC, respectivamente. Os catalisadores avaliados tiveram uma redução de alcatrão 10-45% comparado com o inerte e valores superiores na relação H2:CO e LHV. Os resultados mostraram que o sistema de gaseificação autotérmico permite a transformação da biomassa utilizando catalisadores de custo baixo ou nulo, que o torna atrativo desde o ponto de vista ambiental e econômico. 

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