v. 36 n. 1 (2023): Revista ION
Artigos

Síntese de micro e nanopartículas de efluentes de decapagem da indústria de galvanização a quente

Alejandro Ramírez Marín
Universidad Nacional de Colombia - Sede Medellín
María José Vásquez Canabal
Universidad Nacional de Colombia - Sede Medellín
Luz Marina OCAMPO CARMONA
Universidad Nacional de Colombia

Publicado 2023-02-28

Palavras-chave

  • Palavras-chave: galvanização por imersão a quente, decapagem, nanopartículas, síntese química, ferro, zinco.

Como Citar

Ramírez Marín, A., Torres de la Ossa, J. D., Torres Perdomo, M. F., Vásquez Canabal, M. J., & OCAMPO CARMONA, L. M. (2023). Síntese de micro e nanopartículas de efluentes de decapagem da indústria de galvanização a quente. REVISTA ION, 36(1), 49–58. https://doi.org/10.18273/revion.v36n1-2023004

Resumo

O processo de galvanização a quente é uma das técnicas de proteção contra corrosão mais utilizadas para o aço e consiste na imersão da peça de aço em um banho de zinco fundido. Este processo consiste em várias etapas e cada uma delas produz resíduos sólidos ou efluentes com teor metálico. Esses resíduos giram em torno de 1 000 000 t/ano em todo o mundo. O descarte seguro desses importantes é de grande importância para a proteção do meio ambiente. A etapa mais crítica desse processo é a decapagem, que gera efluentes muito complexos de tratar, mas de interesse para a obtenção de materiais de valor agregado. Neste artigo, micro e nanopartículas de ferro e zinco são obtidas a partir de quatro diferentes rotas de síntese química utilizando efluentes de decapagem da indústria de galvanização a quente como solução de partida, através de coprecipitação e síntese sol-gel, obtendo partículas de diferentes tamanhos, morfologias e estruturas cristalinas.

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Referências

  1. Culcasi A, Gueccia R, Randazzo S, Cipollina A, Micale G. Design of a novel membrane-integrated waste acid recovery process from pickling solution. J. Clean. Prod. 2019;236:117623. doi.org/10.1016/j.jclepro.2019.117623
  2. Magalhães JM, Silva JE, Castro FP, Labrincha JA. Physical and chemical characterisation of metal finishing industrial wastes. J. Environ. Manage. 2005;75(2):157–166. doi.org/10.1016/j.jenvman.2004.09.011
  3. Pérez-Villarejo L, S. Martínez-Martínez S, Carrasco-Hurtado B, Eliche-Quesada D, Ureña-Nieto C, Sánchez-Soto PJ. Valorization and inertization of galvanic sludge waste in clay bricks. Appl. Clay Sci. 2015;105–106:89–99. doi.org/10.1016/j.clay.2014.12.022
  4. Schmidt B, Wolters R, Kaplin J, Schneiker T, Lobo-Recio MA, López F, et al. Rinse water regeneration in stainless steel pickling. Desalination. 2007;211(1–3):64–71. doi.org/10.1016/j.desal.2006.03.591
  5. Silva AC, Mello-Castellano S, Guitian F, Montero I, Esteban-Cubillo A, Sobrados I, et al. Incorporation of galvanic waste (Cr, Ni, Cu, Zn, Pb) in a soda-lime-borosilicate glass. J. Am. Ceram. Soc. 2008;91(4):1300–1305. doi.org/10.1111/j.1551-2916.2008.02311.x
  6. Scheer G, Huckshold M. Design and Manufacturing according to Hot-Dip Galvanizing Requirements. En: Handbook of Hot-Dip Galvanization. Maaß P, Peißker P. Germany: WILEY-VCH; 2011. p. 239-289. doi.org/10.1002/9783527636884.ch7
  7. Hernández JD. Detection of the critical points of the hot-dip galvanizing process: a focus on sustainability and sustainable development (tesis de maestria). Medellín, Colombia: Universidad Nacional de Colombia; 2018. doi.org/10.13140/RG.2.2.19244.56960
  8. Sinha MK, Pramanik S, Sahu SK, Prasad LB, Jha MK, Pandey BD. Development of an efficient process for the recovery of zinc and iron as value added products from the waste chloride solution. Sep. Purif. Technol. 2016;167:37–44. doi.org/10.1016/j.seppur.2016.04.049
  9. Bao S, Tang L, Li K, Ning P, Peng J, Guo H, et al. Highly selective removal of Zn(II) ion from hot-dip galvanizing pickling waste with amino-functionalized Fe3O4@SiO2 magnetic nano-adsorbent. J. Colloid Interface Sci. 2016;462:235–242. doi.org/10.1016/j.jcis.2015.10.011
  10. Guo B, Liu B, Yang J, Zhang S. The mechanisms of heavy metal immobilization by cementitious material treatments and thermal treatments: A review. J. Environ. Manage. 2017;193:410–422. doi.org/10.1016/j.jenvman.2017.02.026
  11. Zhang M, Chen C, Mao L, Wu Q. Use of electroplating sludge in production of fired clay bricks: Characterization and environmental risk evaluation. Constr. Build. Mater. 2018;159:27–36. doi.org/10.1016/j.conbuildmat.2017.10.130
  12. Lian J, Ouyang Q, Tsang PE, Fang Z. Fentonlike catalytic degradation of tetracycline by magnetic palygorskite nanoparticles prepared from steel pickling waste liquor,” Appl. Clay Sci. 2019;182:105273 doi.org/10.1016/j.clay.2019.105273
  13. Li Y, Chen D, Fan S, Yang T. Enhanced visible light assisted Fenton-like degradation of dye via metal-doped zinc ferrite nanosphere prepared from metal-rich industrial wastewater. J. Taiwan Inst. Chem. Eng. 2019;96:185–192. doi.org/10.1016/j.jtice.2018.11.006
  14. Zueva SB, Ferella F, Innocenzi V, De Michelis I, Corradini V, Ippolito NM, et al. Recovery of zinc from treatment of spent acid solutions from the pickling stage of galvanizing plants. Sustain. 2021;13(1):1–8. doi.org/10.3390/su13010407
  15. Akbari A, Amini M, Tarassoli A, Eftekhari-Sis B, Ghasemian N, Jabbari E. Transition metal oxide nanoparticles as efficient catalysts in oxidation reactions. Nano-Structures & Nano-Objects. 2018;14:19–48. doi.org/10.1016/j.nanoso.2018.01.006
  16. Roy SD, Das KC, Dhar SS. Conventional to green synthesis of magnetic iron oxide nanoparticles; its application as catalyst, photocatalyst and toxicity: A short review. Inorg. Chem. Commun. 2021;134:109050. doi.org/10.1016/j.inoche.2021.109050
  17. Doolette CL, Read TL, Howell NR, Cresswell T, Lombi E. Zinc from foliar-applied nanoparticle fertiliser is translocated to wheat grain: A 65Zn radiolabelled translocation study comparing conventional and novel foliar fertilisers. Sci. Total Environ. 2020;749:142369. doi.org/10.1016/j.scitotenv.2020.142369
  18. Andhare DD, Jadhav SA, Khedkar MV, Somvanshi SB, More SD, Jadhav KM. Structural and Chemical Properties of ZnFe2O4 Nanoparticles Synthesised by Chemical Co-Precipitation Technique. J. Phys. Conf. Ser. 2020;1644(1):012014. doi.org/10.1088/1742-6596/1644/1/012014
  19. Kang F, Wu M, Xiao B, Chen R, Wei Y, Liu H, et al. Facile synthesis of schwertmannite@akaganeite core/shell nanostructure from pickling waste liquor: Formation mechanism and potential application. J. Clean. Prod. 2020;260:120961. doi.org/10.1016/j.jclepro.2020.120961
  20. Picasso G, Vega J, Uzuriaga R, Ruiz GP. Synthesis of nanoparticles of magnetite by sol-gel and precipitation methods: study of chemical composition and structure. Rev Soc Quim Perú. 2012;78(3):170–182.
  21. Vinosha PA, Mely LA, Jeronsia JE, Krishnan S, Das SJ. Synthesis and properties of spinel ZnFe2O4 nanoparticles by facile co-precipitation route. Optik (Stuttg). 2017;134:99–108. doi.org/10.1016/j.ijleo.2017.01.018
  22. Verma A, Kore R, Corbin DR, Shiflett MB. Metal Recovery Using Oxalate Chemistry: A Technical Review. Ind. Eng. Chem. Res. 2019;58(34):15381–15393. doi.org/10.1021/acs.iecr.9b02598
  23. Mehrizadeh H, Niaei A, Tseng HH, Salari D, Khataee A. Synthesis of ZnFe2O4 nanoparticles for photocatalytic removal of toluene from gas phase in the annular reactor. J. Photochem. Photobiol. A Chem. 2017;332:188–195. doi.org/10.1016/j.jphotochem.2016.08.028
  24. Sonu, Sharma S, Dutta V, Raizada P, Hosseini-Bandegharaei A, Thakur V, et al. An overview of heterojunctioned ZnFe2O4 photocatalyst for enhanced oxidative water purification. J. Environ. Chem. Eng. 2021;9(5):105812. doi.org/10.1016/j.jece.2021.105812
  25. Abrahams SC, Bernstein JL. Remeasurement of the structure of hexagonal ZnO. Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem. 1969;25(7):1233–1236. doi.org/10.1107/s0567740869003876
  26. Verwey EJW, Heilmann EL. Physical properties and cation arrangement of oxides with spinel structures I. Cation arrangement in spinels. J. Chem. Phys. 1947;15(4):174–180. doi.org/10.1063/1.1746464