Pronóstico de estabilidad de asfaltenos en petróleo crudo con base en análisis SARA mediante redes neuronales artificiales
Publicado 2021-12-10
Palabras clave
- Asfaltenos,
- estabilidad,
- estadística multivariante,
- petróleo crudo,
- SARA
Cómo citar
Derechos de autor 2021 Universidad Industrial de Santander
Esta obra está bajo una licencia internacional Creative Commons Atribución 4.0.
Resumen
La estabilidad del petróleo o su tendencia a producir precipitación de asfaltenos debe ser estimada, debido a su importancia para predecir problemas de obstrucciones de tuberías y equipos de procesos. A partir de las fracciones de hidrocarburos componentes del petróleo, denominadas fracciones SARA (Saturados, Aromáticos, Resinas y Asfaltenos) se han generado índices para estimar la condición de estabilidad con base en las relaciones de solubilidad e insolubilidad de los asfaltenos respecto a las otras fracciones a partir de estudios de laboratorio y análisis matemático. En la presente investigación se analiza la aplicabilidad de pruebas estadísticas multivariantes por Redes Neuronales Artificiales (RNA) para pronosticar la condición de estabilidad determinada a partir de dos índices, la Inestabilidad Coloidal (CII) y el Índice de Estabilidad (IE), además se proponen modificaciones de rangos con base en los resultados y un índice basado en la solubilidad/insolubilidad (IIS). Se utilizó como muestra de estudio 193 análisis SARA de petróleos de diferentes países obtenidas de artículos publicados en revistas científicas para la creación de la RNA, con la que se pronosticó el porcentaje de clasificación correcta basada en la interacción y tendencia de relaciones entre las cuatro fracciones en su conjunto. Adicionalmente se utilizaron 11 muestras externas a las utilizadas en el modelo RNA para validar el mismo. Se obtuvo que laRNA clasificó correctamente el 92,75% de la condición de estabilidad determinada con el CII y 88,60% respecto al IE. El ajuste de los rangos de estabilidad mejoró el pronóstico a 97,41% respecto al CII y 96,89% con el IE. El uso del IIS demostró un menor ajuste según la RNA con 98,45% de casos correctamente clasificados. Se demostró la aplicabilidad de la metodología de RNA para clasificar la condición de estabilidad de muestras de petróleo con base en sus fracciones SARA.
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Referencias
- Akbarzadeh, K., Allenson, S., Creek, J., & Jamaluddin, A. (2007). Asphaltenes-Problematic but Rich in Potential. Oilfield Review, 9(2), 22-48
- Akmaz, S., Iscan, O., Gurkaynak, M.A., & Yasar, M. (2011). The Structural Characterization of Saturate, Aromatic, Resin, and Asphaltene Fractions of Batiraman Crude Oil. Petroleum Science and Technology, 29,160–17. doi: 10.1080/10916460903330361
- Alonso-Ramírez, G., Cuevas-García, R., Sánchez-Minero, F., Ramírez, J., Moreno-Montiel, M., Ancheyta, J., & Carbajal-Vielman, R. (2020). Catalytic hydrocracking of a Mexican heavy oil on a MoS2/Al2O3 catalyst: I. Study of the transformation of isolated saturates fraction obtained from SARA analysis. Catalysis Today, 353, 153-162. doi: 10.1016/j.cattod.2019.07.031
- Arya, A., von Solms, N., & Kontogeorgis, G. M. (2015). Determination of Asphaltene Onset Conditions using the Cubic Plus Association Equation of State. Fluid Phase Equilibria, 400, 8-19. doi: 10.1016/j.fluid.2015.04.032
- Ashoori, S., Sharifi, M., Masoumi, M., & Salehi, M.M. (2017). The relationship between SARA fractions and crude oil stability. Egyptian Journal of Petroleum, 26, 209-213. doi: 10.1016/j.ejpe.2016.04.002
- Aske, N., Kallevik, H., & Sjöblom, J. (2001). Determination of Saturate, Aromatic, Resin, and Asphaltenic (SARA) Components in Crude Oils by Means of Infrared and Near-Infrared Spectroscopy. Energy & Fuels, 15, 1304-1312. doi: 10.1021/ef010088h
- Asomaning, S. (2003). Test Methods for Determining Asphaltene Stability in Crude Oils. Petroleum Science and Technology, 21(3-4), 581-590. doi: 10.1081/LFT-120018540
- Asomaning, S., & Watkinson, A.P. (2000). Petroleum Stability and Heteroatom Species Effects in Fouling of Heat Exchangers by Asphaltenes. Heat Transfer Engineering, 21(3), 10-16. doi: 10.1080/014576300270852
- ASTM D2007. (2011). Standard Test Method for Characteristic Groups in Rubber Extender and Processing Oils and Other Petroleum-Derived Oils by the Clay-Gel Absorption Chromatographic Method. West Conshohocken, PA: American Society for Testing and Materials
- Basheer, I.A., & Hajmeer, M. (2000). Artificial neural networks: fundamentals, computing, design, and application. Journal of Microbiological Methods, 43(1), 3–31. doi: 10.1016/s0167-7012(00)00201-3
- Bisht, H., Reddy, M., Malvanker, M., Patil, R.C., Gupta, A., Hazarika, B., & Das, A.K. (2013). Efficient and Quick Method for Saturates, Aromatics, Resins, and Asphaltenes Analysis of Whole Crude Oil by Thin-Layer Chromatography−Flame Ionization Detector. Energy & Fuels, 27, 3006-3013. doi: 10.1021/ef4002204
- Brahma, K.K., Bendedouch, D., Bouhadda, Y., Bouanani, F., Bounaceur, B., & Sardi, A. (2019). Stability of Hassi-messaoud Asphaltenes in Media of Different Polarities. Petroleum Chemistry, 59(11), 1190–1194. doi: 10.1134/s0965544119110094
- Campen, S., Moorhouse, S.J., & Wong, J.S.S. (2019). Mechanism of an asphaltene inhibitor in different depositing environments: Influence of colloid stability. Journal of Petroleum Science and Engineering, 106502. doi: 10.1016/j.petrol.2019.106502.
- Carnahan, N., Salager, J-L., & Antón, R. (2007, April 30-May 3). Effect of Resins on Stability of Asphaltenes [Conference presentation]. Offshore Technology Conference, Houston, Texas, United States. doi: 10.4043/19002-ms
- Chamkalani, A., Mohammadi, A.H., Eslamimanesh, A., Gharagheizi, F., & Richon, D. (2012). Diagnosis of asphaltene stability in crude oil through ‘‘two parameters’’ SVM model. Chemical Engineering Science, 81, 202–208. doi: 10.1016/j.ces.2012.06.060
- Cheshkova, T.V., Kovalenko, E.Y., Sergun, V.P., Gerasimova, N.N., Sagachenko, T.A., & Min, R.S. (2019). Oil Resins and Asphaltenes of Different Chemical Nature. Chemistry for Sustainable Development, 1, 78-85. doi: 10.15372/CSD20190113
- Codină, G.G., Dabija, A., & Oroian, M. (2019). Prediction of Pasting Properties of Dough from Mixolab Measurements Using Artificial Neuronal Networks. Foods, 8(10), 447-459. doi: 10.3390/foods8100447
- Fan, T., & Buckley, J. S. (2002). Rapid and Accurate SARA Analysis of Medium Gravity Crude Oils. Energy & Fuels, 16, 1571-1575. doi: 10.1021/ef0201228
- Fan, T., Wang, J., & Buckley, J. S. (2002). Evaluating Crude Oils by SARA Analysis. [Conference presentation]. SPE Annual Technical Conference and Exhibition, Tulsa, Oklahoma, USA. doi: 10.2118/75228-MS
- Galvis, L.V., Ochoa, C.A., Arguello, H., Carvajal, J.M., & Calderón, Z.H. (2011). Estimación de propiedades mecánicas de roca utilizando inteligencia artificial. Ingeniería y Ciencia, 7(14), 83-103
- García, P., y Sancho, J. (2010). Estimación de densidad de probabilidad mediante ventanas de Parzen. Jornadas de introducción a la investigación de la UPCT, 3, 68-70. Recuperado de: https://dialnet.unirioja.es/servlet/articulo?codigo=3709476
- Gaspar, A., Zellermann, E., Lababidi, S., Reece, J., & Schrader, W. (2012). Characterization of Saturates, Aromatics, Resins, and Asphaltenes Heavy Crude Oil Fractions by Atmospheric Pressure Laser Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Energy & Fuels, 26, 3481-3487. doi: 10.1021/ef3001407
- Gestal, M. (2013). Introducción a las redes neuronales Recuperado de: https://tinyurl.com/yywe7338
- Guzmán, R., Ancheyta, J., Trejo, F., & Rodríguez, S. (2017). Methods for determining asphaltene stability in crude oils. Fuel, 188, 530–543. doi: 10.1016/j.fuel.2016.10.012
- Hannisdal, A., Hemmingsen, P.V., & Sjöblom, J. (2005). Group-Type Analysis of Heavy Crude Oils Using Vibrational Spectroscopy in Combination with Multivariate Analysis. Industrial & Engineering Chemistry Research, 44, 1349-1357. doi: 10.1021/ie0401354
- Hascakir, B. (2017, October 9-11). A New Approach to Determine Asphaltenes Stability [Conference presentation]. SPE Annual Technical Conference and Exhibition, San Antonio, Texas, USA. doi: 10.2118/187278-ms
- Kök, M. V., Karacan, Ö., & Pamir, R. (1998). Kinetic Analysis of Oxidation Behavior of Crude Oil SARA Constituents. Energy & Fuels, 12, 580-588. doi: 10.1021/ef970173i
- Kok, M.V., & Gul, K.G. (2013). Thermal characteristics and kinetics of crude oils and SARA fractions. Thermochimica Acta, 569, 66-70. doi: 10.1016/j.tca.2013.07.014
- Kök, M.V., Varfolomeev, M.A., & Nurgaliev, D.K. (2019). Determination of SARA fractions of crude oils by NMR technique. Journal of Petroleum Science and Engineering, 179, 1-6. doi: 10.1016/j.petrol.2019.04.026
- Lamus, C., Guzmán, A., Murcia, B., Cabanzo, R., & Mejía-Ospino, E. (2011). Uso de Análisis Multivariado En La Determinación SARA De Crudos Por Espectroscopia NIR. Revista Colombiana de Física, 43(3), 635-642.
- Likhatsky, V.V., & Syunyaev, R.Z. (2010). New Colloidal Stability Index for Crude Oils Based on Polarity of Crude Oil Components. Energy & Fuels, 24(12), 6483–6488. doi: 10.1021/ef101033p
- Liu, P., Shi, Q., Chung, K.H., Zhang, Y., Pan, N., Zhao, S., & Xu, C. (2010). Molecular Characterization of Sulfur Compounds in Venezuela Crude Oil and Its SARA Fractions by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Energy & Fuels, 24, 5089–5096. doi: 10.1021/ef100904k
- Madh, M., Kharrat, R., & Hamoule, T. (2017). Screening of inhibitors for remediation of asphaltene deposits: Experimental and modeling study. Petroleum. doi: 10.1016/j.petlm.2017.08.001.
- Mahmoud, M.B., & Aboujadeed, A.A. (2017). Compatibility Assessment of Crude Oil Blends Using Different Methods. Chemical Engineering Transactions, 57, 1705-1710. doi: 10.3303/CET1757285
- Mansoori, G. (2009). A unified perspective on the phase behaviour of petroleum fluids. International Journal Oil, Gas and Coal Technology, 2(2), 141-167
- Mateus, S.P., González, N., y Branch, J.W. (2014). Aplicación de Redes Neuronales Artificiales en Entornos Virtuales Inteligentes. Información Tecnológica, 25(5), 103-112. doi: 10.4067/S0718-07642014000500015
- Meléndez, L.V., Lache, A., Orrego-Ruiz, J.A., Pachón, Z., & Mejía-Ospino, E. (2012). Prediction of the SARA analysis of Colombian crude oils using ATR–FTIR spectroscopy and chemometric methods. Journal of Petroleum Science and Engineering, 91, 56-60. doi: 10.1016/j.petrol.2012.04.016
- Mohammadi, M., Khorrami, M.K., Vatani, A., Ghasemzadeh, H., Vatanparast, H., Bahramian, A., & Fallah, A. (2021). Genetic algorithm based support vector machine regression for prediction of SARA analysis in crude oil samples using ATR-FTIR spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 245, 118945. doi: 10.1016/j.saa.2020.118945
- Morantes, L.R., Percebom, A.M., & Mejía-Ospino, E. (2019). On the molecular basis of aggregation and stability of Colombian asphaltenes and their subfractions. Fuel, 241, 542-549. doi: 10.1016/j.fuel.2018.12.028
- Pérez, M.F., Rozo, M.A., Ulloa, R., Enrique, F., & Calderón, Z. (2002). Aplicación de las redes neuronales al estudio de yacimientos de petróleo. Fuentes, el reventón energético, 2(2), 76-90
- Prakoso, A., Punase, A., & Klock, K. (2016). Determination of the Stability of Asphaltenes Through Physicochemical Characterization of Asphaltenes. [Conference presentation]. SPE Annual Technical Conference and Exhibition, Anchorage, Alaska, USA. doi: 10.2118/180422-MS
- Punase, A., & Hascakir, B. (2017). Stability Determination of Asphaltenes through Dielectric Constant Measurements of Polar Oil Fractions. Energy & Fuels, 31(1), 65-72. doi: 10.1021/acs.energyfuels.6b01045
- Recknagel, F., & Wilson, H. (2000). Elucidation and Prediction of Aquatic Ecosystems by Artificial Neuronal Networks. In Lek, S., & Guégan, J.F. (Eds.), Artificial Neuronal Networks. Environmental Science. Berlin: Springer. doi: 10.1007/978-3-642-57030-8_10
- Rezaee, S., Tavakkoli, M., Doherty, R., & Vargas, F.M. (2020). A new experimental method for a fast and reliable quantification of saturates, aromatics, resins, and asphaltenes in crude oils. Petroleum Science and Technology, 38(21), 955-961. doi: 10.1080/10916466.2020.1790598
- Riveros, L., Jaimes, B., Ranaudo, M.A., Castillo, J., & Chirinos, J. (2006). Determination of Asphaltene and Resin Content in Venezuelan Crude Oils by Using Fluorescence Spectroscopy and Partial Least Squares Regression. Energy & Fuels, 20, 227-230. doi: 10.1021/ef0501243
- Romero, J.F., Feitosa, F.X., Do Carmo, F.R., & De Sant’Ana, H.B. (2018). Paraffin effects on the stability and precipitation of crude oil asphaltenes: Experimental onset determination and phase behavior approach. Fluid Phase Equilibria, 474, 116-125. doi: 10.1016/j.fluid.2018.07.017
- Safaie, K., & Naza, A. (2014). Evaluation of Asphaltene Inhibitors Effect on Aggregation Coupled Sedimentation Process. Journal of Dispersion Science and Technology, 35(3), 329-337
- Sánchez-Minero, F., Ancheyta, J., Silva-Oliver, G., & Flores-Valle, S. (2013). Predicting SARA composition of crude oil by means of NMR. Fuel, 110, 318-321.doi: 10.1016/j.fuel.2012.10.027
- Santos, D.C., Filipakis, S.D., Rolemberg, M.P., Lima, E.R.A., Paredes, M.L.L. (2017). Asphaltene flocculation parameter in Brazilian crude oils and synthetic polar and nonpolar mixtures: Experimental and modeling. Fuel, 199, 606–615.doi: 10.1016/j.fuel.2017.03.024
- Santos, J.M., Vetere, A., Wisniewski, A., Eberlin, M.N., & Schrader, W. (2020). Modified SARA Method to Unravel the Complexity of Resin Fraction(s) in Crude Oil. Energy & Fuels, 34(12), 16006–16013. doi: 10.1021/acs.energyfuels.0c02833
- Sepúlveda, J., Bonilla, J., y Medina, Y. (2010). Predicción de la Estabilidad de los Asfaltenos Mediante la Utilización del Análisis SARA para Petróleos Puros. Revista Ingeniería y Región, 7(1), 103-110.
- Solaimany, A.R., & Bayandory, L. (2008). Investigation of Asphaltene Stability in the Iranian Crude Oils. Iranian Journal of Chemical Engineering, 5(1), 3-12.
- Speight, J.G. (2004). Petroleum Asphaltenes Part 1. Asphaltenes, Resins and the Structure of Petroleum. Oil & Gas Science and Technology – Rev. IFP, 59(5), 467-477.
- Sulaimon, A.A., & Govindasamy, K. (2015, October 20-22). New Correlation for Predicting Asphaltene Deposition [Conference presentation]. SPE/IATMI Asia Pacific Oil & Gas Conference and Exhibition, Nusa Dua, Bali, Indonesia. doi: 10.2118/176436-ms
- Sulaimon, A.A., De Castro, J.K.M., & Vatsa, S. (2019). New correlations and deposition envelopes for predicting asphaltene stability in crude oils. Journal of Petroleum Science and Engineering, 106782. doi: 10.1016/j.petrol.2019.106782.
- Syunyaev, R.Z., & Likhatsky, V.V. (2010). Effects of Temperature and Pressure on the Phase State of Oils and Asphaltene Solutions Observed Using Dielectric Spectroscopy. Energy & Fuels, 24, 2233–2239. doi: 10.1021/ef900819p
- Tatar, A., Shokrollahi, A., Halali, M.A., Azari, V., & Safari, H. (2015). A Hybrid Intelligent Computational Scheme for Determination of Refractive Index of Crude Oil Using SARA Fraction Analysis. The Canadian Journal of Chemical Engineering, 93, 1547–1555. doi: 10.1002/cjce.22257
- Torkaman, M., Bahrami, M., & Dehghani, M. (2017). Influence of Temperature on Aggregation and Stability of Asphaltenes. I. Perikinetic Aggregation. Energy & Fuels, 31(10), 11169-11180. doi: 10.1021/acs.energyfuels.7b00417
- Torkaman, M., Bahrami, M., & Dehghani, M.R. (2018). Influence of Temperature on Aggregation and Stability of Asphaltenes: II. Orthokinetic Aggregation. Energy & Fuels, 32(5), 6144-6154. doi: 10.1021/acs.energyfuels.7b03601
- Torres-Faurrieta, L.K., Dreyfus-León, M.J., & Rivas, D. (2016). Recruitment forecasting of yellowfin tuna in the eastern Pacific Ocean with artificial neuronal networks. Ecological Informatics, 36, 106–113. doi: 10.1016/j.ecoinf.2016.10.005
- Villada, F., Arroyave, D., & Villada, M. (2014). Pronóstico del Precio del Petróleo mediante Redes Neuronales Artificiales. Información tecnológica, 25(3), 145-154. doi: 10.4067/S0718-07642014000300017
- Wei, B., Zou, P., Shang, J., Gao, K., Li, Y., Sun, L., & Pu, W. (2018). Integrative determination of the interactions between SARA fractions of an extra-heavy crude oil during combustion. Fuel, 234, 850-857. doi: 10.1016/j.fuel.2018.07.127
- Xiong, R., Guo, J., Kiyingi, W., Feng, H., Sun, T., Yang, X., & Li, Q. (2020). Method for Judging the Stability of Asphaltenes in Crude Oil. ACS Omega, 5, 21420−2142. doi: 10.1021/acsomega.0c01779
- Yuan, C-D., Varfolomeev, M.A., Emelianov, D.A., Eskin, A.A., Nagrimanov, R.N., Kok, M.V., Afanasiev, I.S., Fedorchenko, G.D., & Kopylova, E.V. (2017). Oxidation Behavior of Light Crude Oil and Its SARA Fractions Characterized by TG and DSC Techniques: Differences and Connections. Energy & Fuels, 32(1), 801–808. doi: 10.1021/acs.energyfuels.7b02377
- Zhao, S., Pu, W., Sun, B., Gu, F., & Wang, L. (2019a). Comparative evaluation on the thermal behaviors and kinetics of combustion of heavy crude oil and its SARA fractions. Fuel, 239, 117-125. doi: 10.1016/j.fuel.2018.11.014
- Zhao, S., Pu, W., Yuan, C., Peng, X., Zhang, J., Wang, L., & Emelianov, D.A. (2019b). Thermal Behavior and Kinetic Triplets of Heavy Crude Oil and Its SARA Fractions during Combustion by High-Pressure Differential Scanning Calorimetry. Energy & Fuels, 33(4), 3176−3186.doi: 10.1021/acs.energyfuels.9b00399
- Zheng, F., Shi, Q., Salvato, G., Giusti, P., & Bouyssiere, B. (2020). Fractionation and Characterization of Petroleum Asphaltene: Focus on Metalopetroleomics. Processes, 8, 1504-1535. doi: 10.3390/pr8111504