Artigos
Biofuel production from thermocatalytic processing of vegetable oils: A review
Publicado 2015-12-03
Palavras-chave
- Biofuels,
- Pyrolysis,
- Hydroprocessing,
- Vegetable oils
Como Citar
H. Zandonai, C. , Ortiz Bravo, C., & Fernandes Machado, N. (2015). Biofuel production from thermocatalytic processing of vegetable oils: A review. REVISTA FUENTES, 13(2). https://doi.org/10.18273/revfue.v13n2-2015008
Resumo
With the worsening environmental problems caused by the greenhouse effect, the study of fuel alternatives generated by non-fossil sources has intensifi ed. The incorporation of biodiesel (mono-ester of triglycerides) to petroleum diesel is an example of commercial application for reduction in the emission of fossil CO2 and sOx and nOx as well. in this context, the generation of mixture of hydrocarbons for catalytic cracking of vegetable oils combines the advantages of the Transesterifi cation process to generate compounds such as petroleum-derived fuels such as: gasoline, kerosene and diesel. This review presents current trends in scientifi c literature for biofuels from thermal (pyrolysis) and catalytic processing. For the pyrolysis it has been described the temperatures use to obtain the fuel in the diesel range. the catalytic processing involves the heterogeneous catalysts used in the processing crude oil and the conditions of temperature and pressure. in conclusion it is showed that the cracking catalytic process allows chose what fuel does one want simply changing the catalytic that is used.
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Referências
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3. Asomaning, J., Mussone, P., & Bressler, D. C. (2014a). Pyrolysis of polyunsaturated fatty acids. Fuel Processing Technology, 120, 89–95. http://doi. org/10.1016/j.fuproc.2013.12.007
4. Asomaning, J., Mussone, P., & Bressler, D. C. (2014b). Thermal deoxygenation and pyrolysis of oleic acid. Journal of Analytical and Applied Pyrolysis, 105, 1–7. http://doi.org/10.1016/j. jaap.2013.09.005
5. Bezergianni, S., Dimitriadis, A., & Meletidis, G. (2014). Effectiveness of CoMo and NiMo catalysts on co-hydroprocessing of heavy atmospheric gas oil-waste cooking oil mixtures. Fuel, 125, 129–136. http://doi.org/10.1016/j.fuel.2014.02.010
6. Biswas, S., Majhi, S., Mohanty, P., Pant, K. K., & Sharma, D. K. (2014). Effect of different catalyst on the co-cracking of Jatropha oil, vacuum residue and high density polyethylene. Fuel, 133, 96–105. http:// doi.org/10.1016/j.fuel.2014.04.082
7. Biswas, S., & Sharma, D. K. (2013). Studies on cracking of Jatropha oil. Journal of Analytical and Applied Pyrolysis, 99, 122–129. http://doi. org/10.1016/j.jaap.2012.10.013
8. Buzetzki, E., Sidorová, K., Cvengrošová, Z., Kaszonyi, A., & Cvengroš, J. (2011). The influence of zeolite catalysts on the products of rapeseed oil cracking. Fuel Processing Technology, 92(8), 1623– 1631. http://doi.org/10.1016/j.fuproc.2011.04.009
9. Casas, A., Ramos, M. J., & Pérez, Á. (2011a). Kinetics of chemical interesterification of sunflower oil with methyl acetate for biodiesel and triacetin production. Chemical Engineering Journal, 171(3), 1324–1332. http://doi.org/10.1016/j.cej.2011.05.037
10. Casas, A., Ramos, M. J., & Pérez, Á. (2011b). New trends in biodiesel production: Chemical interesterification of sunflower oil with methyl acetate. Biomass and Bioenergy, 35(5), 1702–1709. http://doi.org/10.1016/j.biombioe.2011.01.003
11. Casas, A., Ramos, M. J., & Pérez, Á. (2013). Methanol-enhanced chemical interesterification of sunflower oil with methyl acetate. Fuel, 106(865), 869–872. http://doi.org/10.1016/j.fuel.2012.11.037
12. Chen, Y., Wang, C., Lu, W., & Yang, Z. (2010). Study of the co-deoxy-liquefaction of biomass and vegetable oil for hydrocarbon oil production. Bioresource Technology, 101(12), 4600–7. http:// doi.org/10.1016/j.biortech.2010.01.071
13. Choudhary, T. V., & Phillips, C. B. (2011). Renewable fuels via catalytic hydrodeoxygenation. Applied Catalysis A: General, 397(1-2), 1–12. http:// doi.org/10.1016/j.apcata.2011.02.025
14. Doronin, V. P., Potapenko, O. V., Lipin, P. V., & Sorokina, T. P. (2013). Catalytic cracking of vegetable oils and vacuum gas oil. Fuel, 106, 757– 765. http://doi.org/10.1016/j.fuel.2012.11.027
15. Doronin, V. P., Potapenko, O. V., Lipin, P. V., Sorokina, T. P., & Buluchevskaya, L. a. (2012). Catalytic cracking of vegetable oils for production of high-octane gasoline and petrochemical feedstock. Petroleum Chemistry, 52(6), 392–400. http://doi. org/10.1134/S0965544112060059
16. Dupain, X., Costa, D. J., Schaverien, C. J., Makkee, M., & Moulijn, J. (2007). Cracking of a rapeseed vegetable oil under realistic FCC conditions. App. Cat. B: Env., 72(1-2), 44–61. http://doi. org/10.1016/j.apcatb.2006.10.005
17. Egia, B., Cambra, J. ., Arias, P. ., Güemez, M. ., Legarreta, J. ., Pawelec, B., & Fierro, J. L. . (1998). Surface properties and hydrocracking activity of NiMo zeolite catalysts. Applied Catalysis A: General, 169(1), 37–53. http://doi.org/10.1016/ S0926-860X(97)00320-7
18. Egloff, G., & Morrell, J. C. (1932). The Cracking of Cottonseed Oil. Industrial & Engineering Chemistry, 24(12), 1426–1427. http://doi.org/10.1021/ ie50276a020
19. Egloff, G., & Nelson, E. F. (1933). Cracking Alaskan Fur-Seal Oil. Industrial & Engineering Chemistry, 25(4), 386–387. http://doi.org/10.1021/ie50280a009
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