Artículos
Síntesis y optimización de propiedades de películas delgadas de FAx(MA1-X)PbI3 crecidas por spin coating con estructura perovskita para ser usadas como capa activa en celdas solares híbridas
Gerardo Gordillo-Guzmán- Ophyr Virgüez-Amaya
- Camilo Otálora-Bastidas
- Clara Calderón-Triana
- César Quiñones-Segura
Publicado 2020-01-03
Palabras clave
- composición química,
- catión methylammonium,
- catión formamidinium,
- tratamiento antisolvente
Cómo citar
Gordillo-Guzmán, G., Virgüez-Amaya, O., Otálora-Bastidas, C., Calderón-Triana, C., & Quiñones-Segura, C. (2020). Síntesis y optimización de propiedades de películas delgadas de FAx(MA1-X)PbI3 crecidas por spin coating con estructura perovskita para ser usadas como capa activa en celdas solares híbridas. Revista UIS Ingenierías, 19(1), 87–94. https://doi.org/10.18273/revuin.v19n1-2020008
Derechos de autor 2020 Revista UIS Ingenierías
Esta obra está bajo una licencia internacional Creative Commons Atribución-SinDerivadas 4.0.
Resumen
Este trabajo reporta resultados relacionados con el efecto que la sustitución del catión methylammonium por el catión formamidinium causa sobre las propiedades de las películas de FAx(MA1-x)PbI3 sintetizadas por spin coating en un paso. Para esto se realizó un estudio que estableciera la influencia de la composición de las películas de FAx(MA1-x)PbI3 sobre sus propiedades ópticas, estructurales y morfológicas, determinadas a través de medidas de transmitancia espectral, microscopía de fuerza atómica y difracción de rayos-X. Correlacionando parámetros de síntesis con los resultados del estudio de propiedades realizado fue posible obtener las condiciones para crecer películas de FAx(MA1-x)PbI3 con gap óptico mejorado, microestructura y morfología, que permite pensar que este compuesto es adecuado para ser usado como capa activa en celdas solares híbridas.
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Referencias
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[5] C. Chien-Hung, W. Chun-Guey, “Bulk heterojunction perovskite: PCBM solar cells with high fill factor”, Nature Photonics, vol. 10, no.3, pp. 196-200, 2016. doi: 10.1038/nphoton.2016.3.
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[7] M.M. Lee et al., “Efficient hybrid solar cells based on meso-superstructured, organometal Halide perovskites”, Science, vol. 338, pp. 643-647, 2012. doi: 10.1126/science.1228604
[8] J. Burschka et al., “Sequential deposition as a route to high-performance perovskite-sensitized solar cells”, Nature, vol. 499, pp. 316-319, 2013. doi: 10.1038/nature12340.
[9] O. Malinkiewicz et al., “Perovskite solar cells employing organic charge-transport layers”, Nature Photonics, vol. 8, pp. 128-132, 2014. doi: 10.1038/nphoton.2013.341.
[10] S.D. Stranks et al., “Electron-hole diffusion lengths exceeding 1 micrometer in an organometal Trihalide perovskite absorber”, Science, vol. 342, no. 6156, pp. 341-344, 2013. doi: 10.1126/science.1243982.
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[16] S. Xu-Guang et al., “Effect of CH3NH3I concentration on the physical properties of solution-processed organometal halide perovskite CH3NH3PbI3”, Journ. of Alloys and Compounds, vol. 706, pp. 274-279, 2017. doi: 10.1016/j.jallcom.2017.02.256.
[17] Z. Yi et al., “Optimization of stable quasi-cubic; FAxMA1-xPbI3 perovskite structure for solar cells with efficiency beyond 20%”, ACS Energy Lett, vol. 2, pp. 802-806, 2017. doi: 10.1021/acsenergylett.7b00112.
[18] K. Nitu, P.L. Sanjaykumar, G.L. Jignasa, “Superior efficiency achievement for FAPbI3-perovskite thin film solar cell by optimization with response surface methodology technique and partial replacement of Pb by Sn”, Optik, vol. 176, pp. 262-277, 2019. doi: 10.1016/j.ijleo.2018.09.066.
[19] M. Saliba et al., “Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance”, Science, vol. 354, no. 6309, pp. 206-209, 2016. doi: 10.1126/science.aah5557.
[20] J. M. Frost et al., “Atomistic origins of high-performance in hybrid halide perovskite solar cells”, Nano Lett., vol. 14, no. 5, pp. 2584-2590, 2014. doi: 10.1021/nl500390f.
[21] W. Qiu et al., “An interdiffusion method for highly performing cesium/formamidinium double cation perovskites”, Adv. Funct. Mater.,
vol. 27, no. 28, 1700920, 2017. doi: 10.1002/adfm.201700920.
[22] R. Yogamalar et al., “X-ray peak broadening analysis in ZnO nanoparticles”, Solid State Commun, vol. 149, pp. 1919-1923, 2009. doi: 10.1016/j.ssc.2009.07.043.
[23] G. K. Williamson and W. H. Hall, “X-ray line broadening from filed aluminium and wolfram,” Acta Metall., vol. 1, no. 1, pp. 22–31, 1953, doi: 10.1016/0001-6160(53)90006-6.
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[26] B. Slimi et al., “Perovskite FA1-xMAxPbI3 for solar cells: film formation and properties”, Energy Procedia, vol. 102, pp. 87-95, 2016. doi: 10.1016/j.egypro.2016.11.322.
[27] Y. Li, et al., “Formamidinium-based lead halide perovskites: structure, properties, and fabrication methodologies”, Small Methods, vol. 2, no. 7, 2018. doi: 10.1002/smtd.201700387.