Artículos
Estudio y simulación de un gasificador con captura de CO2 para la producción de hidrógeno azul partiendo de carbón colombiano
Orlando Castiblanco-Urrego- Harvey Andrés Milquez-Sanabria
Publicado 2021-07-16
Palabras clave
- carbón,
- hidrógeno,
- gas de síntesis,
- gasificación,
- dióxido de carbono
- carbón colombiano,
- Aspen HYSYS,
- antracítico,
- bituminoso ...Más
Cómo citar
Castiblanco-Urrego, O., & Milquez-Sanabria, H. A. (2021). Estudio y simulación de un gasificador con captura de CO2 para la producción de hidrógeno azul partiendo de carbón colombiano. Revista UIS Ingenierías, 20(4), 91–100. https://doi.org/10.18273/revuin.v20n4-2021007
Resumen
En esta investigación se hizo el diseño y la simulación de un gasificador de carbón con captura de dióxido de carbono para la obtención de hidrógeno, mediante el software Aspen HYSYS versión 9.0; se utilizó como materia prima carbón antracítico y bituminoso, procedente de diferentes regiones de Colombia. Las características del carbón, así como las condiciones de los demás flujos de alimentación al reactor, inciden en las condiciones finales del gas producto en la simulación. Una vez iniciado el análisis de sensibilidad en el simulador, se logra observar el comportamiento de estas variables, es decir, las condiciones de la alimentación, con lo cual se pueden fijar los intervalos de operación para el proceso. Los resultados obtenidos son teóricamente viables, y pueden ser utilizados como base para casos reales en la industria energética, ya que en la actualidad Colombia posee una de las mayores reservas de carbón en Latinoamérica.
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Referencias
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[2] R. A. Huggins, Energy storage, 2nd ed. New York, NY, USA: Springer, 2010.
[3] S. Dutta, “A review on production, storage of hydrogen and its utilization as an energy resource”, Journal of Industrial and Engineering Chemistry, vol. 20, no. 4, pp. 1148-1156, 2014, doi: 10.1016/j.jiec.2013.07.037.
[4] R. B. Gupta, Hydrogen fuel: production, transport, and storage. Boca Raton, FL, USA: Crc Press, 2008.
[5] E. E. S. Michaelides, Alternative energy sources. Fort Worth, TX, USA: Springer Science & Business Media, 2012.
[6] F. Dawood, M. Anda, G. M. Shafiullah, “Hydrogen production for energy: An overview”, International Journal of Hydrogen Energy, vol. 45, no. 7, pp. 3847-3869, 2020, doi: 10.1016/j.ijhydene.2019.12.059.
[7] L. Cao et al., “Biorenewable hydrogen production through biomass gasification: A review and future prospects”, Environmental research, vol. 186, pp. 109547, 2020, doi: 10.1016/j.envres.2020.109547.
[8] H. Ju, S. Badwal, S. Giddey, “A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production”, Applied Energy, vol. 231, pp. 502-533, 2018, doi: 10.1016/j.apenergy.2018.09.125.
[9] H. Lin et al., “CO2-selective membranes for hydrogen production and CO2 capture–Part I: Membrane development”, Journal of membrane science, vol. 457, pp. 149-161, 2014, doi: 10.1016/j.memsci.2014.01.020.
[10] M. Voldsund, K. Jordal, R. Anantharaman. “Hydrogen production with CO2 capture”, International Journal of Hydrogen Energy, vol. 41, no. 9, pp. 4969-4992, 2016, doi: 10.1016/j.ijhydene.2016.01.009.
[11] N. V. Gnanapragasam, B. V. Reddy, M. A. Rosen, “Hydrogen production from coal gasification for effective downstream CO2 capture”, International Journal of Hydrogen Energy, vol. 35, no. 10, pp. 4933-4943, 2010, doi: 10.1016/j.ijhydene.2009.07.114.
[12] A. Boretti, “Production of hydrogen for export from wind and solar energy, natural gas, and coal in Australia”, International Journal of Hydrogen Energy, vol. 45, no. 7, pp. 3899-3904, 2020, doi: 10.1016/j.ijhydene.2019.12.080.
[13] T. R. Paul, H. Nath, V. Chauhan, A. Sahoo, “Gasification studies of high ash Indian coals using Aspen plus simulation”, Materials Today: Proceedings, 2020, doi: 10.1016/j.matpr.2020.04.033.
[14] T. R. Cruzado Urbina, L. M. García Rodríguez, “Diseño y simulación de un gasificador para el aprovechamiento de las reservas de carbón del alto chicama”, trabajo de grado, Universidad Nacional de Trujillo, 2017.
[15] R. B. Zapata, J. F. P. Bayer, C. S. Jiménez, “Carbones colombianos: clasificación y caracterización termoquímica para aplicaciones energéticas”, Revista ION, vol. 27, no. 2, pp. 43-54, 2014.
[16] L. J. M. Umaña, El carbón: origen, atributos, extracción y usos actuales en Colombia. Bogotá, Colombia: Universidad Nacional de Colombia, 2014.
[17] American Society for Testing and Materials (ASTM), Standard Classification of Coals by Rank, ASTM D388-12, 2012.
[18] J. F. P. Bayer, R. B. Zapata, C. S. Jiménez, Producción de gas natural sintético mediante gasificación de carbones colombianos: análisis termodinámico con Aspen Plus®. Colombia: Editorial Universidad de Antioquia, 2015.
[19] J. G. Speight, Handbook of coal analysis, 2nd ed. USA: John Wiley and Sons, 2015.
[20] U. D. UPME, “La cadena del carbón”, Ministerio de Minas y Energía, 2012 [En línea]. Disponible en: https://www.upme.gov.co/Docs/Cadena_carbon.pdf.
[21] IEA-International Energy Agency, “Key Coal Trends, Excerpt from: Coal information”, 2016 [En línea]. Disponible en: https://euagenda.eu/upload/publications/untitled-69166-ea.pdf .
[22] A. Cardoso, “Valuation languages along the coal chain from Colombia to the Netherlands and to Turkey”, Ecological Economics, vol. 146, pp. 44-59, 2018, doi: 10.1016/j.ecolecon.2017.09.012.
[23] J. Davison, S. Arienti, P. Cotone, L. Mancuso, “Co-production of hydrogen and electricity with CO2 capture”, International Journal of Greenhouse Gas Control, vol. 4, no. 2, pp. 125-130, 2010, doi: 10.1016/j.ijggc.2009.10.007.
[24] D. Osborne, The Coal Handbook: Towards Cleaner Production: Volume 2: Coal Utilisation. India: Elsevier, 2013.
[25] D. A. Bell, B. F. Towler, y M. Fan, Coal gasification and its applications. Great Britain: William Andrew, 2010.
[26] I. C. López, C. R. Ward, “Composition and mode of occurrence of mineral matter in some Colombian coals”, International Journal of Coal Geology, vol. 73, no. 1, pp. 3-18, 2008, doi: 10.1016/j.coal.2007.03.005.
[27] H. Watanabe, R. Kurose, “Modeling and simulation of coal gasification on an entrained flow coal gasifier”, Advanced Powder Technology, vol. 31, no. 7, pp. 2733-2741, 2020, doi: 10.1016/j.apt.2020.05.002.
[28] Z. Dai, R. D. Noble, D. L. Gin, X. Zhang, L. Deng, “Combination of ionic liquids with membrane technology: A new approach for CO2 separation”, Journal of Membrane Science, vol. 497, pp. 1-20, 2016, doi: 10.1016/j.memsci.2015.08.060.
[29] T. A. Peters et al., “Palladium (Pd) membranes as key enabling technology for pre-combustion CO2 capture and hydrogen production”, Energy Procedia, vol. 114, pp. 37-45, 2017, doi: 10.1016/j.egypro.2017.03.1144.
[30] M. Gazzani, G. Manzolini, “Using palladium membranes for carbon capture in integrated gasification combined cycle (IGCC) power plants”, en Palladium Membr. Technol. Hydrog. Prod. Carbon Capture Other Appl. Princ. Energy Prod. Other Appl., United Kingdom: Elsevier, 2014.2014, pp. 221-246.
[31] AspenTech, Aspen HYSYS Help Section, Aspen Technology, Inc., Burlington, MA, USA: 2011.
[32] C. F. Palma, A. D. Martin, “Model based evaluation of six energy integration schemes applied to a small-scale gasification process for power generation”, Biomass and Bioenergy, vol. 54, pp. 201-210, 2013, doi: 10.1016/j.biombioe.2013.03.024.