Articles
Mechanical and thermal characteristics of a polyurethane processed from hyguerilla oil (ricinus communis) for the adhesion of structural elements of guadua angustifolia kunth
Published 2020-07-29
Keywords
- adhesive,
- castor oil,
- thermal diffusivity,
- specific heat,
- photoacoustic
- thermal relaxation,
- mechanical resistance ...More
How to Cite
Gordillo-Delgado, F., Bedoya-Pérez, A. F., & Delgado-Osorio, H. D. (2020). Mechanical and thermal characteristics of a polyurethane processed from hyguerilla oil (ricinus communis) for the adhesion of structural elements of guadua angustifolia kunth. Revista UIS Ingenierías, 19(4), 103–114. https://doi.org/10.18273/revuin.v19n4-2020009
Copyright (c) 2020 Revista UIS Ingenierías
This work is licensed under a Creative Commons Attribution-NoDerivatives 4.0 International License.
Abstract
In recent decades, the search for raw from renewable resources to produce polymers, elastomers, resins, foams, etc., has intensified; these materials would reduce the industrial use of petrochemical compounds. In this work, the oil extracted from the castor oil seed (Ricinus communis) was used because of ricinoleic acid content (92.3%), it is of easy production and non-edible vegetable origin. The polyurethane adhesive was synthesized through transesterification and polymerization reactions. Using the corresponding standards, this adhesive was applied to sheets of Guadua angustifolia Kunth for determining its mechanical characteristics, the compressive strength parallel to the fiber was 43±3 (MPa), and shear parallel to the fiber was 5.9±0.9 (MPa). Fourier transform infrared spectroscopy was used for determining the appropriate molar ratio and monitoring the reaction during the synthesis and final product structure was analyzed with X-ray diffraction. Through differential scanning calorimetry, the glass transition temperature of the product was estimated on -24.6 °C; the thermal relaxation technique was used to measure its specific heat, while its thermal diffusivity and thermal expansion coefficient were estimated with the photoacoustic technique.
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References
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[14] I. M. Sulastiningsih, Nurwati, “Physical and mechanical properties of laminated bamboo board”, Journal of Tropical Forest Science, vol. 21, no. 3, pp. 246-251, 2009.
[15] H. M. Cleuren, A. B. Henkemans, “Development of the bamboo sector in Ecuador: harnessing the potential of Guadua angustifolia”, J Bamboo and Rattan, vol. 2, no. 2, pp. 179-188, 2003.
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[24] H. J. C. Velásquez, J. A. Osorio-Saraz, J. M. Vélez- Restrepo, “Determinación de la resistencia mecánica a tensión y cizalladura de la Guadua angustifolia Kunth”, Rev. Fac. Nal. Agr., vol. 58, no. 1, pp. 2709-2715, 2005, doi: 10.15446/rfnam
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[26] A. Lara-Bernal, E. Marín, A. Calderón, “Técnica de relajación térmica con excitación variable: caso de la ‘rampa’ de intensidad”, Superficies y vacío, vol. 20, no. 3, pp. 17-20, 2007.
[27] J. McHugh, P. Fideu, A. Herrmann , W. Stark, “Determination and review of specific heat capacity measurements during isothermal cure of an epoxy using TM-DSC and standard DSC techniques”, Polymer
Testing, vol. 29, pp. 759-765, 2010, doi: 10.1016/j.polymertesting.2010.04.004
[28] M. H. Kalele, Y. Zhu, M. C. Mulenga, “Preparation and Characterization of Waterborne Polyurethane Crosslinked by Urea Bridges International”, Journal of Chemistry, vol. 3, no. 2, pp. 88-96, 2011, doi: 10.5539/ijc.v3n2p88
[29] A. Bedoya, E. Marín, A. M. Mansanares, M.A. Zambrano-Arjona, I. Riech, A. Calderón, “On the thermal characterization of solids by photoacoustic calorimetry Thermal diffusivity and linear thermal expansion coefficient”, Thermochimica Acta, vol. 614, pp. 52-58, 2015, doi: 10.1016/j.tca.2015.06.009
[30] R. D. Adams, R. D. Adams, J. Comyn, W. C. Wake, Structural Adhesive Joints in Engineering, Netherlands: Springer Science & Business Media, 1997.
[31] A. Bedoya, F. Gordillo-Delgado, y E. Marín, “Measurement of the thermal expansion coefficient of Guadua angustifolia Kunth using the photoacoustic technique”, Journal of Physics: Conference Series, vol. 687, pp. 1-4, 2016, doi: 10.1088/1742-6596/687/1/012103
[32] K. Y. Li,n, C.M. Fleischmann, M. J. Spearpoint, “Determining thermal physical properties of pyrolyzing New Zealand medium density fibreboard (MDF)”, Chemical Engineering Science, vol. 95, pp. 211-220, 2013, doi: 10.1016/j.ces.2013.03.019
[33] H. P. S. Abdul Khalil, I. U. H. Bhat, M. Jawaid, A. Zaidon, D. Hermawan, Y. S. Hadi, “Bamboo fibre reinforced biocomposites: A review”, Materials & Design, vol. 42, pp. 353-368, 2012, doi: 10.1016/j.matdes.2012.06.015